Recent Advances in Superabsorbent Hydrogels Derived from Agro Waste Materials for Sustainable Agriculture: A Review.

Superabsorbent hydrogels made from agro waste materials have the potential to promote sustainable agriculture and environmental sustainability. These hydrogels not only help reduce water consumption and increase crop yields but also contribute to minimizing waste and lowering greenhouse gas emissions. Recent research on superabsorbent hydrogels derived from agro wastes has focused on the preparation of hydrogels based on natural polymers isolated from agro wastes, such as cellulose, hemicellulose, and lignin. This review provides an in-depth examination of hydrogels developed from raw agro waste materials and natural polymers extracted from agro wastes, highlighting that these studies start with raw wastes as the main materials. The utilization strategies for specific types of agro wastes are comprehensively described. This review outlines different methods utilized in the production of these hydrogels, including physical cross-linking techniques such as dissolution-regeneration and freeze-thawing, as well as chemical cross-linking methods involving various cross-linking agents and graft polymerization techniques such as free radical polymerization, microwave-assisted polymerization, and γ radiation graft polymerization. Specifically, this review explores the applications of agro waste-based superabsorbent hydrogels in enhancing soil properties such as water retention and slow-release of fertilizers for sustainable agriculture.