Perovskites have been largely implemented into optoelectronics as they provide several advantages such as long carrier diffusion length, high absorption coefficient, high carrier mobility, shallow defect levels and finally, high crystal quality. The brisk technological development of perovskite devices is connected to their relative simplicity, high-efficiency processing and low production cost. Significant improvement has been made in the detection performance and the photodetectors' design, especially operating in the visible (VIS) and near-infrared (NIR) regions. This paper attempts to determine the importance of those devices in the broad group of standard VIS and NIR detectors. The paper evaluates the most important parameters of perovskite detectors, including current responsivity (), detectivity (*) and response time (), compared to the standard photodiodes (PDs) available on the commercial market. The conclusions presented in this work are based on an analysis of the reported data in the vast pieces of literature. A large discrepancy is observed in the demonstrated and *, which may be due to two reasons: immature device technology and erroneous * estimates. The published performance at room temperature is even higher than that reported for typical detectors. The utmost * for perovskite detectors is three to four orders of magnitude higher than commercially available VIS PDs. Some papers report a * close to the physical limit defined by signal fluctuations and background radiation. However, it is likely that this performance is overestimated. Finally, the paper concludes with an attempt to determine the progress of perovskite optoelectronic devices in the future.
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http://dx.doi.org/10.3390/ma17164029 | DOI Listing |
Nat Commun
January 2025
State Key Laboratory of Radiation Medicine and Protection, Collaborative Innovation Center of Radiological Medicine of Jiangsu Higher Education Institutions, and School for Radiological and Interdisciplinary Sciences (RAD-X), Soochow University, Suzhou, China.
High intrinsic detection efficiency is as decisive as high energy resolution. Scaling up detector volume has presented great challenges, preventing perovskite semiconductors from reaching sufficient detection efficiency. We report a hole-only virtual-Frisch-grid CsPbBr detector up to 2.
View Article and Find Full Text PDFChem Commun (Camb)
January 2025
Wuhan National Laboratory for Optoelectronics and School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan 430074, China.
Quasi-2D DJ type perovskites theoretically offer excellent properties for X-ray detection, but they often face issues such as phase segregation and small crystal size. In this study, we synthesized large single crystals of quasi-2D DJ type perovskite (3AMPY)(MA)PbBr using temperature-controlled crystallization. The resulting X-ray detector exhibited high resistivity (1.
View Article and Find Full Text PDFACS Appl Mater Interfaces
December 2024
School of Optoelectronic Science and Engineering, University of Electronic Science and Technology of China (UESTC), Chengdu 610054, PR China.
Low-dimensional hybrid organic-inorganic perovskites (HOIPs) containing chiral organic ligands have recently emerged as promising candidates for circularly polarized light (CPL) detection, which can distinguish left- and right-handed CPL directly. However, the increase in responsivity and realization of self-powered CPL photodetector remain a challenge. Meanwhile, there is a trade-off between the photocurrent responsivity and the ability to differentially absorb CPL in detectors based on these low-dimensional perovskites.
View Article and Find Full Text PDFAdv Mater
December 2024
State Key Laboratory of Luminescent Materials and Devices, School of Materials Science and Engineering, South China University of Technology, Guangzhou, 510640, China.
The emerging metal halide perovskites are challenging the traditional scintillators in the field of radiation detection and radiography. However, they lack the capability for remote and real-time radiation monitoring and imaging in confined and hostile conditions. To address this issue, details on an inorganic scintillating glass fiber incorporating perovskite quantum dots (QDs) as highly efficient pixelated radiation emitters are reported, while the glass fibers themselves serve at the same time as low-loss waveguides, enabling long-distance and underwater X-ray detection.
View Article and Find Full Text PDFSmall
December 2024
Wuhan National Laboratory for Optoelectronics and School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan, Hubei Province, 430074, China.
3D and 2D organic hybrid perovskites, as well as double perovskites, have demonstrated their suitability for direct X-ray detection. However, the sensitivity and stability of 3D perovskite X-ray detectors are currently being hindered by the existing constraints on ion movement. Therefore, there is an immediate need to develop X-ray detectors that are both highly sensitive and stable while also being environmentally friendly.
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