The phenomenon of rate-dependent adhesion has long been recognized as an intricate problem, and the so-far-developed physics and mechanics-based approaches resulted in analytical relations between the implicit form between the work of adhesion and the contact front velocity which are difficult to implement in practice. To address this issue in the framework of spherical indentation, the adhesion relaxation test in a nominal point contact is introduced to estimate the rate-dependent adhesion. Based on a stretched exponent approximation for the contact radius evolution with time, a relatively simple four-parameter model is proposed for the functional relation between the work of adhesion and the contact front velocity, and its fitting performance is compared to that of the known Greenwood-Johnson and Persson-Brener models.
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http://dx.doi.org/10.3390/ma17163944 | DOI Listing |
ACS Appl Mater Interfaces
January 2025
Department of Materials and Environmental Chemistry, Stockholm University, Svante Arrhenius väg 16C, 10691 Stockholm, Sweden.
There is a growing demand for biobased functional materials that can ensure targeted pesticide delivery and minimize active ingredient loss in the agricultural sector. In this work, we demonstrated the use of esterified lignin nanoparticles (ELNPs) as carriers and controlled-release agents of hydrophobic compounds. Curcumin was selected as a hydrophobic model compound and was incorporated during ELNP fabrication with entrapment efficiencies exceeding 95%.
View Article and Find Full Text PDFLangmuir
November 2024
School of Materials and Chemical Technology, Tokyo Institute of Technology, 2-12-1, O-Okayama, Meguro-ku, Tokyo 152-8552, Japan.
Adhesive contact phenomena play a crucial role in various scientific and engineering fields. However, considering viscoelasticity, which is essential for understanding practical applications involving soft materials like polymers, makes analysis challenging. Traditional elastic contact models such as the Johnson-Kendall-Roberts and Maugis-Dugdale models often fail to account for viscoelastic behavior.
View Article and Find Full Text PDFBioinspir Biomim
October 2024
Mechanics, Mathematics and Management, Polytechnic University of Bari, via E. Orabona 4, Bari, 70125, ITALY.
The contact behaviour of mushroom-shaped pillars has been extensively studied for their superior adhesive properties, often inspired by natural attachment systems observed in insects. Typically, pillars are modeled with linear elastic materials in the literature; in reality, the soft materials used for their fabrication exhibit a rate-dependent constitutive behaviour. Additionally, conventional models focus solely on the detachment phase of the pillar, overlooking the analysis of the attachment phase.
View Article and Find Full Text PDFMaterials (Basel)
August 2024
Institut für Mechanik, Technische Universität Berlin, 10623 Berlin, Germany.
The phenomenon of rate-dependent adhesion has long been recognized as an intricate problem, and the so-far-developed physics and mechanics-based approaches resulted in analytical relations between the implicit form between the work of adhesion and the contact front velocity which are difficult to implement in practice. To address this issue in the framework of spherical indentation, the adhesion relaxation test in a nominal point contact is introduced to estimate the rate-dependent adhesion. Based on a stretched exponent approximation for the contact radius evolution with time, a relatively simple four-parameter model is proposed for the functional relation between the work of adhesion and the contact front velocity, and its fitting performance is compared to that of the known Greenwood-Johnson and Persson-Brener models.
View Article and Find Full Text PDFbioRxiv
September 2024
Department of Civil and Environmental Engineering, University of Illinois Urbana-Champaign.
Unlabelled: Delivery of drug using nanocarriers tethered with vasculature-targeting epitopes aims to maximize the therapeutic efficacy of the drug while minimizing the drug side effects. Circadian rhythm which is governed by the central nervous system has implications for targeted drug delivery due to sleep-wake cycle changes in blood flow dynamics. This paper presents an advanced fluid dynamics modeling method that is based on viscous incompressible shear-rate fluid (blood) coupled with an advection-diffusion equation to simulate the formation of drug concentration gradients in the blood stream and buildup of concentration at the targeted site.
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