The seminal isolation of a dinuclear rare earth metal complex comprising a bridging 2,2'-azobispyridyl radical anion, [(CpY)(μ-abpy˙)](BPh), is presented, which was obtained from a one-electron chemical oxidation of [(CpY)(μ-abpy)]. The unprecedented compounds were characterized by crystallography, spectroscopy and DFT computations. The radical character was proven by EPR spectroscopy.
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| http://dx.doi.org/10.1039/d4cc03222e | DOI Listing |
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