The current coverage of direct, high-quality ship-based observations of surface ocean pCO includes large gaps in time and space, and has been declining since 2017. These ocean observations provide the basis for the data products that reconstruct surface ocean pCO and estimate ocean carbon uptake. Improved data coverage is needed to advance our understanding of the ocean carbon sink and air-sea CO exchange. Targeted sampling from autonomous platforms, such as biogeochemical floats, combined with traditional shipboard measurements represents a promising path forward to improve surface ocean pCO reconstructions. However, floats provide indirect pCO estimates derived from pH, and thus have higher uncertainty and are biased compared to direct shipboard measurements. Here, we use a Large Ensemble Testbed (LET) of Earth System Models and the pCO-Residual method to reconstruct surface ocean pCO globally to test the impact of additional float observations, both with and without measurement uncertainties. Through comparison to the 'model truth', the LET allows for robust evaluation of the reconstructions. With only shipboard sampling, surface ocean pCO is overestimated, and the 2000-2016 global ocean carbon sink is underestimated by 0.1 Pg C year. Additional float observations significantly reduce this underestimation, and deviate from the 'model truth' by as little as 0.01 Pg C year, even when floats have random uncertainties of ± 11 μatm. However, systematic bias in the float observations significantly degrades the accuracy of pCO reconstructions, leading to an even stronger underestimation of the global ocean carbon sink of up to 0.32 Pg C year. We conclude that adding float-based observations to the global observing system can significantly improve reconstructions of global surface ocean pCO, but only if these data are unbiased.
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http://dx.doi.org/10.1038/s41598-024-70617-x | DOI Listing |
RSC Adv
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Jiangsu Key Laboratory of Marine Biological Resources and Environment, Jiangsu Ocean University Lianyungang 222005 China
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Tennenbaum Marine Observatories Network, Smithsonian Environmental Research Center, Edgewater, Maryland, USA.
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January 2025
Shandong Ocean Pipe Technology Co., Ltd, Dezhou 253300, China.
Polymeric coatings that combine resistance to adhesion ("defending") and killing ("attacking") of biocontaminants were proposed to endow the surface with nonadhesive and bactericidal capabilities. In contrast, a zwitterionic copolymer P(GMA--DMAPS) with antifouling groups ([2-(methacryloyloxy)ethyl]dimethyl-(3-sulfopropyl)ammonium hydroxide, DMAPS) and a zwitterionic/cationic copolymer P(GMA--DMAPS--DMC) with bactericidal groups ([2-(methacryloyloxy)ethyl]trimethylammonium chloride, DMC) were synthesized, of which the latter exhibited synergistic inhibitory and killing properties. The distinct feed ratios of monomers were conducted, and the optimal molar ratio was obtained.
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School of Minerals Processing and Bioengineering, Central South University, Changsha 410083, PR China. Electronic address:
Bubble-microplastic (MP) interaction is a significant process that changes the routes of MP circulation in marine environment and thereby determines the risk of MPs, which could be strongly influenced by natural organic matter (NOM) in oceans. However, the quantitative interaction mechanisms between bubbles and MPs under the effect of NOM remain elusive. Herein, bubble-MP interactions in simulated seawater were quantified at nanoscale based on atomic force microscope coupled with the Stokes-Reynold-Young-Laplace model.
View Article and Find Full Text PDFPLoS One
January 2025
Institute for Global Ecology, Florida Institute of Technology, Melbourne, Florida, United States of America.
Marine heatwaves are increasing in intensity and frequency however, responses and survival of reef corals vary geographically. Geographical differences in thermal tolerance may be in part a consequence of intraspecific diversity, where high-diversity localities are more likely to support heat-tolerant alleles that promote survival through thermal stress. Here, we assessed geographical patterns of intraspecific genetic diversity in the ubiquitous coral Pocillopora damicornis species complex using 428 sequences of the Internal Transcribed Spacer 2 (ITS2) region across 44 sites in the Pacific and Indian Oceans.
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