In this work, starting from an approach previously proposed by the Authors, we put forward an extension to the large deformation regime of the dimensionally-reduced formulation for peridynamic thin plates, including both hyperelasticity and fracture. In particular, the model, validated against numerical simulations, addresses the problem of the peeling in nonlocal thin films, which when attached to a soft substrate highlights how nonlocality of the peeled-off layer might greatly influence the whole structural response and induce some unforeseen mechanical behaviours that could be useful for engineering applications. Through a key benchmark example, we in fact demonstrate that de-localization of damage and less destructive failure modes take place, these effects suggesting the possibility of conceiving specific networks of nonlocal interactions between material particles, corresponding to lattice-equivalent structure of the nonlocal model treated, of interest in designing new material systems and interfaces with enhanced toughness and adhesive properties.
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http://dx.doi.org/10.1007/s11012-024-01786-2 | DOI Listing |
Commun Mater
January 2025
Physik-Institut, Universität Zürich, Zürich, Switzerland.
The discovery of unconventional superconductivity often triggers significant interest in associated electronic and structural symmetry breaking phenomena. For the infinite-layer nickelates, structural allotropes are investigated intensively. Here, using high-energy grazing-incidence x-ray diffraction, we demonstrate how in-situ temperature annealing of the infinite-layer nickelate PrNiO ( ≈ 0) induces a giant superlattice structure.
View Article and Find Full Text PDFJ Phys Chem Lett
January 2025
DST Unit of Nanoscience (DST UNS) and Thematic Unit of Excellence (TUE), Department of Chemistry, Indian Institute of Technology Madras, Chennai 600036, India.
Clathrate hydrates (CHs) are believed to exist in cold regions of space, such as comets and icy moons. While spectroscopic studies have explored their formation under similar laboratory conditions, direct structural characterization using diffraction techniques has remained elusive. We present the first electron diffraction study of tetrahydrofuran (THF) and 1,3-dioxolane (DIOX) CHs in the form of nanometer-thin ice films under an ultrahigh vacuum at cryogenic temperatures.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Key Laboratory for Advanced Materials and Joint International Research Laboratory of Precision Chemistry and Molecular Engineering, Shanghai Key Laboratory of Functional Materials Chemistry, Feringa Nobel Prize Scientist Joint Research Center, Frontiers Science Center for Materiobiology and Dynamic Chemistry, Institute of Fine Chemicals, School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai, China.
Currently, the development of polymeric hole-transporting materials (HTMs) lags behind that of small-molecule HTMs in inverted perovskite solar cells (PSCs). A critical challenge is that conventional polymeric HTMs are incapable of forming ultra-thin and conformal coatings like self-assembly monolayers (SAMs), especially for substrates with rough surface morphology. Herein, we address this challenge by designing anchorable polymeric HTMs (CP1 to CP5).
View Article and Find Full Text PDFSmall
January 2025
State Key Laboratory of Electronic Thin Films and Integrated Devices, National Engineering Research Center of Electromagnetic Radiation Control Materials, School of Integrated Circuit Science and Engineering, University of Electronic Science and Technology of China, Chengdu, 610054, P. R. China.
Dual-band tungsten oxide (WO) electrochromic films are extensively investigated, yet challenges persist regarding complex fabrication processes and limited cyclic stability. In this paper, a novel approach to prepare graphdiyne quantum dots (GDQDs) doped WO films with a hexagonal crystal structure, is presented. Structural characterization reveals that the GDQDs/WO possesses a coral-like, loose structure with high crystallinity due to the synergistic modulation of morphology and crystallinity.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Institute of New Energy Technology, College of Physics & Optoelectronic Engineering, Jinan University, Guangzhou 510632, China.
The addition of organic cationic iodides to form low-dimensional perovskite is an essential strategy for defect passivation in perovskite solar cells (PSCs). Specially, the 2D/3D perovskite structure can combine the stability of 2D perovskite and the high charge transport performance of 3D perovskite. Here, we introduced phenylammonium hydroiodide salts with different alkyl chain lengths into PSCs precursor solution to research the influence on formation of perovskite thin films and the photovoltaic performance of PSCs.
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