Reactions between [(Tren)UN] (1, Tren = {N(CHCHNSiPr)}) and [M(η-CR)] (M/R = Cr/H, Mn/H, Fe/H, Ni/H) were intractable, but M/R = Co/H or Co/Me afforded [(Tren)UN-(η:η-CH)Co(η-CH)] (2) and [(Tren)U-NH] (3), respectively. For M/R = V/H [(Tren)U-NV(η-CH)] (4), was isolated. Complexes 2-4 evidence one-/two-electron uranium reductions, nucleophilic nitrides, and partial N-atom transfer.
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| http://dx.doi.org/10.1039/d4cc03846k | DOI Listing |
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