A PHP Error was encountered

Severity: Warning

Message: file_get_contents(https://...@pubfacts.com&api_key=b8daa3ad693db53b1410957c26c9a51b4908&a=1): Failed to open stream: HTTP request failed! HTTP/1.1 429 Too Many Requests

Filename: helpers/my_audit_helper.php

Line Number: 176

Backtrace:

File: /var/www/html/application/helpers/my_audit_helper.php
Line: 176
Function: file_get_contents

File: /var/www/html/application/helpers/my_audit_helper.php
Line: 250
Function: simplexml_load_file_from_url

File: /var/www/html/application/helpers/my_audit_helper.php
Line: 3122
Function: getPubMedXML

File: /var/www/html/application/controllers/Detail.php
Line: 575
Function: pubMedSearch_Global

File: /var/www/html/application/controllers/Detail.php
Line: 489
Function: pubMedGetRelatedKeyword

File: /var/www/html/index.php
Line: 316
Function: require_once

Simultaneous immobilization strategy of anionic metalloids and cationic metals in agricultural systems: A review. | LitMetric

Simultaneous immobilization strategy of anionic metalloids and cationic metals in agricultural systems: A review.

Chemosphere

Department of Science and Environmental Studies, The Education University of Hong Kong, Tai Po, Hong Kong Special Administrative Region, 999077, China. Electronic address:

Published: September 2024

AI Article Synopsis

  • Remediating heavy metals in natural environments is complex due to factors such as metal speciation and soil moisture interactions; this review discusses methods for immobilizing both anionic and cationic metals in soil-crop systems.
  • Effective strategies include water management, the use of biochar, and various soil amendments that leverage adsorption, redox reactions, and precipitation mechanisms influenced by soil pH and iron oxides.
  • Combining biochar with iron and other materials can enhance the immobilization of multiple metals while improving soil quality and crop growth, leading to better agricultural outcomes.

Article Abstract

Concurrent heavy metals remediation in natural environments poses significant challenges due to factors like metal speciation and interactions with soil moisture. This review focuses on strategies for immobilizing both anionic and cationic metals simultaneously in soil-crop systems. Key approaches include water management, biochar utilization, stabilizing agents, nanotechnology, fertilization, and bioremediation. Sprinkler or intermittent irrigation combined with soil amendments/biochar effectively immobilizes As/Cd/Pb simultaneously. This immobilization occurs through continuous adsorption-desorption, oxidation-reduction, and precipitation mechanisms influenced by soil pH, redox reactions, and Fe-oxides. Biochar from sources like wine lees, sewage sludge, spent coffee, and Fe-nanoparticles can immobilize As/Cd/Pb/Cr/Co/Cu/Zn together via precipitation. In addition, biochar from rice, wheat, corn straw, rice husk, sawdust, and wood chips, modified with chemicals or nanoparticles, simultaneously immobilizes As and Cd, containing higher FeO, Fe-oxide, and OH groups. Ligand exchange immobilizes As, while ion exchange immobilizes Cd. Furthermore, combining biochar especially with iron, hydroxyapatite, magnetite, goethite, silicon, graphene, alginate, compost, and microbes-can achieve simultaneous immobilization. Other effective amendments are selenium fertilizer, Ge-nanocomposites, Fe-Si materials, ash, hormone, and sterilization. Notably, combining nano-biochar with microbes and/or fertilizers with Fe-containing higher adsorption sites, metal-binding cores, and maintaining a neutral pH could stimulate simultaneous immobilization. The amendments have a positive impact on soil physio-chemical improvement and crop development. Crops enhance production of growth metabolites, hormones, and xylem tissue thickening, forming a protective barrier by root Fe-plaque containing higher Fe-oxide, restricting upward metal movement. Therefore, a holistic immobilization mechanism reduces plant oxidative damage, improves soil and crop quality, and reduces food contamination.

Download full-text PDF

Source
http://dx.doi.org/10.1016/j.chemosphere.2024.143106DOI Listing

Publication Analysis

Top Keywords

simultaneous immobilization
12
cationic metals
8
exchange immobilizes
8
soil
5
immobilization strategy
4
strategy anionic
4
anionic metalloids
4
metalloids cationic
4
metals agricultural
4
agricultural systems
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!