The naphthalimide molecule (NAP) was successfully synthesized and characterized by spectroscopy techniques. The NAP probe was exposed to a solvatochromic and aggregation-induced emission (AIE) probe using UV-visible and PL spectroscopy. In this case, the increased polarity of the solvent shows that it is red-shifted. The probe emission, a sky blue to yellow-green color at hexane to DCM, exhibited an excellent quantum yield. Meanwhile, the high-polar solvents of DMF and DMSO had poor quantum yields. This probe NAP showed the aggregation-induced emission property dramatically enhanced the emissions (at 540 nm) from f = 80-90%. NAP was conducted with two polar solvent vapors in hexane and chloroform to investigate VOCs in a further solid-state study. A real-life test paper kit NAP probe was prepared and investigated VOCs detection against hexane and chloroform. When exposed to hexane vapors, the NAP probe test kit showed sky blue emission under UV light, which returned to greenish emission upon exposure to chloroform. Therefore, the results show that this NAP probe can be used for gas leak detection applications.
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http://dx.doi.org/10.1007/s10895-024-03903-6 | DOI Listing |
ACS Appl Mater Interfaces
January 2025
University of Michigan - Shanghai Jiao Tong University Joint Institute, Shanghai Jiao Tong University, Shanghai 200240, China.
Proton conducting electrochemical cells (PCECs) are efficient and clean intermediate-temperature energy conversion devices. The proton concentration across the PCECs is often nonuniform, and characterizing the distribution of proton concentration can help to locate the position of rate-limiting reactions. However, the determination of the local proton concentration under operating conditions remains challenging.
View Article and Find Full Text PDFChemistry
January 2025
Shiv Nadar University, CHEMISTRY, NH 91, TEHSIL DADRI, GAUSTAM BUDHA NAGAR, 201314, GREATER NOIDA, INDIA.
Since death is an inevitable phenomenon, exploring cell deaths holds importance. During this process, the cellular microenvironment within cells such as pH, polarity, viscosity etc alter. One such microenvironment, viscosity elevates during different cell deaths.
View Article and Find Full Text PDFBioorg Chem
December 2024
School of Chemistry and Chemical Engineering, Anhui University of Technology, Ma'anshan 243032, PR China. Electronic address:
Peroxynitrite (ONOO) and viscosity are critical indicators of lysosome functionality, intimately linked to numerous diseases' pathophysiological processes. Hence, creating reliable analytical techniques to observe fluctuations in lysosomal ONOO and viscosity is highly important. This study presents the development of a novel naphthalimide-based fluorescent probe, Nap-Cy, specifically designed to target lysosomes and simultaneously detect both ONOO and viscosity.
View Article and Find Full Text PDFChemistry
December 2024
School of Chemical Sciences, Indian Association for the Cultivation of Science (IACS), 2 A and 2B, Raja S. C. Mullick Road, Jadavpur, Kolkata, West Bengal, 700032, India.
Talanta
February 2025
School of Chemistry and Chemical Engineering, Key Laboratory of Ministry of Education for Advanced Materials in Tropical Island Resources, Collaborative Innovation Center of Ecological Civilization, Hainan University, Haikou, 570228, PR China; Key Laboratory of Quality Safe Evaluation and Research of Degradable Material for State Market Regulation, Hainan Academy of Inspection and Testing, Haikou, 571626, PR China. Electronic address:
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