AI Article Synopsis
- Iridium is a crucial but expensive anode catalyst in proton exchange membrane water electrolysis (PEMWE), leading to challenges when trying to reduce its usage due to increased anode polarization.
- A new anode catalyst layer made from one-dimensional iridium nanofiber allows high-performance operation (3 A cm at 1.86 V) with very low iridium loading (0.07 mg cm) and maintains effectiveness even without a platinum-coated transport layer.
- The success of this nanofiber catalyst is attributed to its favorable electronic properties that eliminate issues related to electron transport at the interface, demonstrating the potential for optimizing materials in low-iridium PEMWE applications.
Article Abstract
Iridium, the most widely used anode catalyst in proton exchange membrane water electrolysis (PEMWE), must be used minimally due to its high price and limited supply. However, reducing iridium loading poses challenges due to abnormally large anode polarization. Herein, we present an anode catalyst layer (CL) based on a one-dimensional iridium nanofiber that enables a high current density operation of 3 A cm at 1.86 V, even at an ultralow loading (0.07 mg cm). The performance is maintained even with a Pt coating-free porous transport layer (PTL) because our nanofiber CL circumvents the interfacial electron transport problem caused by the native oxide on the Ti PTL. We attribute this to the low work function and the low-ionomer-exposed surface of the nanofiber CL, which prevent the formation of Schottky contact at the native oxide interface. These results highlight the significance of optimizing the electronic properties of the CL/PTL interface for low-iridium-loading PEMWE.
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| http://dx.doi.org/10.1021/acsnano.4c06373 | DOI Listing |
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