Since 1990, commercial lithium-ion batteries have made significant strides, approaching their theoretical performance limits, albeit with escalating costs. To address these challenges, attention has shifted toward lithium-sulfur batteries, which offer higher theoretical energy densities and cost-effectiveness. However, lithium-sulfur cells face challenges such as active-material loss, excessive electrolyte usage, and rapid degradation of lithium-metal anodes. To overcome these issues, research has focused on optimizing cell configurations and fabrication parameters while exploring novel electrolytes and electrode materials. This feature article delves into the intrinsic material challenges and extrinsic engineering issues in current lithium-sulfur research and explores the development of advanced lithium-sulfur cells with crucial progress on high-loading sulfur cathodes, lean-electrolyte cells, and solid-state electrolytes. Moreover, it outlines the fundamental principles, structures, performances, and developmental trajectories indicated in research articles published after 2020, highlighting future research directions aimed at resolving key challenges for the practical application of lithium-sulfur cells.
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http://dx.doi.org/10.1039/d4cc03085k | DOI Listing |
Adv Mater
January 2025
Tsinghua Shenzhen International Graduate School, Tsinghua University, Shenzhen, 518055, China.
Commercialization of lithium-sulfur (Li-S) batteries is largely limited by polysulfide shuttling and sluggish kinetics. Herein, 2D nanochannel interlayer composed of alternatively-stacked porous silica nanosheets (PSN) and TiCT-MXene are developed. The 2D nanochannels with selective cation transport characteristics facilitate lithium ion rapid transport, while reject the translocation of polysulfide anions across the separator.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
Center for Nanomedicine, Institute for Basic Science (IBS), Seoul 03722, Republic of Korea.
Perpendicular nanochannel creation of two-dimensional (2D) nanostructures requires highly controlled anisotropic drilling processes of the entire structure via void formation. However, chemical approaches for the creation of porosity and defects of 2D nanostructures have been challenging due to the strong basal plane chemical stability and the use of harsh reactants, tending to give randomly corroded 2D structures. In this study, we introduce Lewis acid-base conjugates (LABCs) as molecular drillers with attenuated chemical reactivity which results in the well-defined perpendicular nanochannel formation of 2D TiS nanoplates.
View Article and Find Full Text PDFACS Nano
January 2025
School of Physical Science and Technology, Lanzhou University, 222 South Tianshui Road, Lanzhou 730000, China.
Polysulfide shuttling and dendrite growth are two primary challenges that significantly limit the practical applications of lithium-sulfur batteries (LSBs). Herein, a three-in-one strategy for a separator based on a localized electrostatic field is demonstrated to simultaneously achieve shuttle inhibition of polysulfides, catalytic activation of the Li-S reaction, and dendrite-free plating of lithium ions. Specifically, an interlayer of polyacrylonitrile nanofiber (PNF) incorporating poled BaTiO (PBTO) particles and coating with a layer of MoS (PBTO@PNF-MoS) is developed on the PP separator.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Department of Physics and Astronomy, Clemson University, Clemson, South Carolina 29634, United States.
Solid-state lithium-sulfur (Li-S) batteries show promise for future electric mobility due to their high energy density potential. However, high internal impedance, Li polysulfide shuttling, and dendrite formation exist. Herein, we present a Li-rich cellulosic solid-state electrolyte (SSE) that, when paired with a sulfurized polyacrylonitrile (SPAN) cathode, leads to durable Li-S batteries for use in the room temperature to 50 °C range.
View Article and Find Full Text PDFJ Colloid Interface Sci
December 2024
College of Materials Science and Engineering, Changchun University of Science and Technology, Changchun 130022, China; Key Laboratory of Applied Chemistry and Nanotechnology at Universities of Jilin Province, Changchun University of Science and Technology, Changchun 130022, China. Electronic address:
High-energy-density lithium-sulfur (Li-S) cells are identified as one of the most prospective next-generation energy storage appliances owing to their numerous advantages. Nonetheless, their widespread applications are restricted by the unwanted shuttling effect and tardy conversion reaction kinetics of lithium polysulfides (LiPSs). To address these puzzles, we present an innovative strategy for the one-pot synthesis of LaF@SiO yolk-shell heterostructure nanofibers (YSHNFs) through a straightforward uniaxial electrospinning process coupled with fluorination, avoiding the complexities of traditional methods.
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