An unusual example of a potassium capped terminal cobalt-oxido complex has been isolated and crystallographically characterized. The synthesis of [DHP]CoOK proceeds from a previously reported parent compound, [DHP]CoOH, deprotonation with KOBu. Structural and electronic characterization suggest a weakly coupled dimer in a distinct seesaw geometry with a Co(III) oxidation state and a non-innocent radical ligand.
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| http://dx.doi.org/10.1039/d4cc03014a | DOI Listing |
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