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Exploring high-performance anion exchange membranes (AEM) for water electrolyzers (AEMWEs) is significant for green hydrogen production. However, the current AEMWEs are restricted by the poor mechanical strength and low OH conductivity of AEMs, leading to the low working stability and low current density. Here, we develop a robust AEM with polybiphenylpiperidium network by combining the crosslinking with triazine and the capping with pyridine for advanced AEMWEs. The AEM exhibits an excellent mechanical strength (79.4 MPa), low swelling ratio (19.2 %), persistent alkali stability (≈5,000 hours) and high OH conductivity (247.2 mS cm) which achieves the state-of-the-art AEMs. Importantly, when applied in AEMWEs, the corresponding electrolyzer equipped with commercial nickel iron and nickel molybdenum catalysts obtained a current density of up to 3.0 A cm at 2 V and could be stably operated ~430 h at a high current density of 1.6 A cm, which exceeds the most of AEMWEs. Our results suggest that triazine crosslinking and pyridine capping can effectively improve the overall performance of the AEMWEs.
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