Halide perovskites (HPs) based memristors show great potential in the simulation of biological neurons. Herein, a memristor with Ag/PMMA&CsPbCl/ITO structure is developed by incorporating CsPbCl nanocrystals (NCs) into poly(methyl methacrylate) (PMMA) as the functional layer. The device exhibits typical bipolar resistive behavior, low operating voltage, good endurance of more than 400 cycles, consistent and excellent ON/OFF ratio (≈ 10), and high mechanical bending stability (bending times = 1000). The RS mechanism has been well explained by the electric field induced formation and rupture of Ag filaments in the PMMA&CsPbCl layer. More importantly, the memristor successfully displays fundamental nociceptive functions including threshold, nonadaptation, relaxation, and sensitization (allodynia and hyperalgesia). To demonstrate the feasibility of the artificial nociceptor, a pressure nociceptor system is constructed using the Ag/PMMA&CsPbCl/ITO device. These results provide new perspectives for the development of next-generation, high-performance HPs based neural morphology devices.
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http://dx.doi.org/10.1021/acs.jpclett.4c01944 | DOI Listing |
Adv Sci (Weinh)
December 2024
College of Materials Engineering, Fujian Agriculture and Forestry University, Fuzhou, 350002, China.
Rare-earth-doped all-inorganic perovskite applications for near-infrared (NIR) emission are crucial for the construction of the next generation of intelligent lighting sources. However, the preparation of rare-earth-doped all-inorganic perovskite is complex, and difficult to control, and the issue of thermal quenching poses significant challenges to its practical application. Here, in order to address these issues, a convenient photo-induced synthesis method for CsPbCl:Mn/Yb nanocrystals (NCs) is proposed by decomposing carbon tetrachloride with 365 nm light to provide chloride ions and regulate the formation of perovskite at room temperature.
View Article and Find Full Text PDFThe in-situ generation of perovskite nanocrystals within organic media using a femtosecond laser can greatly simplify the sample preparation process and save pulse energy. In this work, three perovskite nanocrystals (PNCs), CsPbCl, CsPbBrCl, and CsCdxPbBr, were generated in situ within organic media using a femtosecond laser. These three perovskite nanocrystals emitted pure blue or blue-green fluorescence under ultraviolet (UV) irradiation.
View Article and Find Full Text PDFChem Commun (Camb)
October 2024
Department of Chemistry and Biochemistry, Centre for NanoScience Research, Concordia University, 7141 Sherbrooke Street West, Montreal, Quebec, H4B 1R6, Canada.
The self-assembly of CsPbCl perovskite nanocrystals and their Mn-enriched analogs into supercrystals is reported. Increasing Mn content in the nanocrystals leads to formation of larger, increasingly uniform cubic supercrystals that eventually become rod-like with higher photoluminescence quantum yields.
View Article and Find Full Text PDFJ Am Chem Soc
October 2024
Nanochemistry, Istituto Italiano di Tecnologia, Via Morego 30, Genova 16163, Italy.
Adv Mater
November 2024
State Key Laboratory on Integrated Optoelectronics, Key Laboratory of Advanced Gas Sensors of Jilin Province, College of Electronic Science & Engineering, Jilin University, Changchun, 130012, P. R. China.
Metal-halide perovskites have become attractive nanomaterials for advanced biosensors, yet the structural design remains challenging due to the trade-off between environmental stability and sensing sensitivity. Herein, a trinity strategy is proposed to address this issue by integrating Mn (II) substitution with CsPbCl inert shell and NH-PEG-COOH coating for designing Mn-doped CsPbCl/CsPbCl core/shell hetero perovskite nanocrystals (PMCP PNCs). The trinity strategy isolates the emissive Mn-doped CsPbCl core from water and the Mn d-d transition generates photoluminescence with a long lifetime, endowing the NH-PEG-COOH capped Mn-doped CsPbCl/CsPbCl PNCs with robust water stability and oxygen-sensitive property.
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