Bimetallic Ru-Ir/Rh complexes with the Ru-based metalloligand -(bpy)Ru(PPh) (RuP) serve as catalysts for the selective reduction of allyl alcohol to propylene, employing H gas or an electrochemical setup. Metal-metal bonded key π-allyl intermediates [(RuP)M(η-CH)] (M = Ir, Rh) are identified, advancing the understanding of the catalytic processes.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/d4cc01711k | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Bimetallic Ru-Ir/Rh complexes for catalytic allyl alcohol reduction to propylene.
Chem Commun (Camb)
August 2024
Department of Chemistry, Graduate School of Science, Osaka Metropolitan University, 3-3-138 Sugimoto, Sumiyoshi-ku, Osaka City, Osaka 558-8585, Japan.
Bimetallic Ru-Ir/Rh complexes with the Ru-based metalloligand -(bpy)Ru(PPh) (RuP) serve as catalysts for the selective reduction of allyl alcohol to propylene, employing H gas or an electrochemical setup. Metal-metal bonded key π-allyl intermediates [(RuP)M(η-CH)] (M = Ir, Rh) are identified, advancing the understanding of the catalytic processes.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!