A machine vision tool for multi-color HO sensing by MoOx nanoparticles with oxygen vacancies.

Spectrochim Acta A Mol Biomol Spectrosc

Shenzhen Key Laboratory of Ultraintense Laser and Advanced Material Technology, Center for Advanced Material Diagnostic Technology, and College of Engineering Physics, Shenzhen Technology University, Shenzhen 518118, China.

Published: January 2025

Improving the ease of operation and portability of hydrogen peroxide (HO) detection in daily production and life holds significant application value. However, it remains a challenge to achieve rapid colorimetric detection of HO and color change quantification. In this study, we achieved rapid and visual detection of HO by MoOx (2 ≤ x ≤ 3) nanoparticles with rich oxygen vacancies using machine vision. As the concentration of HO increases, the detection system exhibited a visible multi-color change from blue to green and then yellow and the absorption peak near 680 nm measured by the UV-visible spectrophotometer gradually decreased. With excellent sensitivity, a wide linear range of 0.1-600 μmol/L, concentrations as low as 0.1 μmol/L can be detected with good selectivity towards HO. The sensing mechanism of detecting HO by the change of oxygen vacancies in MoOx was revealed through characterization methods such as XPS, EPR, and DFT. In addition, the Hue, Saturation, Value (HSV) visual analysis system based on MoOx was constructed to assist in the rapid, portable, and sensitive monitoring of HO in practical application scenarios. This work offers an easy-to operate, low cost, and convenience for achieving rapid colorimetric determination of HO and has broad application prospects in daily life and industrial production.

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Source
http://dx.doi.org/10.1016/j.saa.2024.124953DOI Listing

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