An additional 100 million tons/year of lignin coproduct will result when lignocellulosic biomass is processed in biorefineries to fiber, sugars, biofuels, and bioproducts. This will double the amount of lignin already generated from pulping and paper production. Unlike pulping that results in lignosulphonate (88% of total) or Kraft lignin (9%), aqueous-based biorefining leaves behind non-sulfonated lignin and aromatic molecules. This new type of lignin provides opportunities for large volume agricultural uses such as controlled-release carriers and soil amendments as well as feedstocks for new chemistries that lead to molecular building blocks for the chemical industry and to precursors for sustainable aviation biofuels.
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http://dx.doi.org/10.1016/j.tibtech.2024.07.004 | DOI Listing |
Trends Biotechnol
November 2024
Department of Agricultural and Biological Engineering, Purdue University, West Lafayette, IN, USA; Laboratory of Renewable Resources Engineering, Purdue University, West Lafayette, IN, USA. Electronic address:
An additional 100 million tons/year of lignin coproduct will result when lignocellulosic biomass is processed in biorefineries to fiber, sugars, biofuels, and bioproducts. This will double the amount of lignin already generated from pulping and paper production. Unlike pulping that results in lignosulphonate (88% of total) or Kraft lignin (9%), aqueous-based biorefining leaves behind non-sulfonated lignin and aromatic molecules.
View Article and Find Full Text PDFACS Appl Mater Interfaces
June 2021
Department of Chemical Engineering, Lakehead University, Thunder Bay, ON, Canada.
Lignin is the richest source of renewable aromatics and has immense potential for replacing synthetic chemicals. The limited functionality of lignin is, however, challenging for its potential use, which motivates research for creating advanced functional lignin-derived materials. Here, we present an aqueous-based acid precipitation method for preparing functional lignin nanoparticles (LNPs) from carboxymethylated or carboxypentylated lignin.
View Article and Find Full Text PDFBiotechnol Lett
July 2021
Bioprocess Engineering Laboratory, School of Chemistry and Food, Universidade Federal Do Rio Grande, Rio Grande, RS, 96203-900, Brazil.
Objective: The effects of monosaccharide constituents of lignocellulosic materials on exopolysaccharide (EPS) production by Mesorhizobium sp. Semia 816 were studied.
Results: According to the results, by using sugars commonly found in lignocellulosic biomass as carbon sources (glucose, arabinose and xylose), no significant differences were observed in the production of EPS, reaching 3.
Int J Biol Macromol
June 2021
Department of Chemical and Materials Engineering, University of Dayton, 300 College Park, Dayton, OH 45469-0256, USA; Integrative Science and Engineering Center, University of Dayton, 300 College Park, Dayton, OH 45469, USA. Electronic address:
This work offers a facile fabrication method for lignin nanocomposites through the assembly of kraft lignin onto magnetic nanoparticles (FeO) based on pH-driven precipitation, without needing organic solvents or lignin functionalization. Kraft lignin@FeO multicore nanocomposites fabrication proceeded using a simple, pH-driven precipitation technique. An alkaline solution for kraft lignin (pH 12) was rapidly injected into an aqueous-based FeO nanoparticle colloidal suspension (pH 7) under constant mixing conditions, allowing the fabrication of lignin magnetic nanocomposites.
View Article and Find Full Text PDFNanoscale
June 2015
School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798.
In this article, alkali lignin (AL)-assisted direct exfoliation of MoS2 mineral into single-layer and few-layer nanosheets in water is reported for the first time. Under optimized conditions, the concentration of MoS2 nanosheets in the obtained dispersion can be as high as 1.75 ± 0.
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