The Pd complex bis-{()-(-)--[(biphenyl-2-yl)methyl-idene]1-(4-meth-oxy-phen-yl)ethanamine-κ}di-chlorido-palladium(II), [PdCl(CHNO)], crystallizes in the monoclinic Sohncke space group 2 with a single mol-ecule in the asymmetric unit. The coordination environment around the palladium is slightly distorted square planar. The N-Pd-Cl bond angles are 91.85 (19), 88.10 (17), 89.96 (18), and 90.0 (2)°, while the Pd-Cl and Pd-N bond lengths are 2.310 (2) and 2.315 (2) Å and 2.015 (2) and 2.022 (6) Å, respectively. The crystal structure features inter-molecular N-H⋯Cl and intramolecular C-H⋯Pd inter-actions, which lead to the formation of a supramolecular framework structure.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC11299657PMC
http://dx.doi.org/10.1107/S2414314624005558DOI Listing

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