Fabrication and characterization of SbO-MoSnanocomposites for high performance supercapacitor applications.

Nanotechnology

Department of Physics, School of Advanced Sciences, Vellore Institute of Technology, Vellore, Tamil Nadu 632014, India.

Published: August 2024

Binary nanocomposite-based electrodes have been studied extensively in recent times owing to their multiple oxidation states, excellent physico-chemical features, and combined morphology, which are suitable for increasing the electrochemical performance of supercapacitors. The present work deals with SbO-MoSnanocomposites electrode for supercapacitor applications. The x-ray diffraction (XRD), Raman, scanning electron microscope (SEM), energy dispersive x-ray (EDX), high-resolution transmission electron microscopy (HRTEM), selected area electron diffraction (SAED) and x-ray photoelectron spectroscopy (XPS) characterizations have been studied to analyze the phase formation, vibrational modes, morphology, elemental composition and binding energies of the prepared SbO-MoSnanocomposites electrode material, as well as their electrochemical measurements such as cyclic voltammetry (CV), galvanostatic charge-discharge (GCD), and electrochemical impedance spectroscopy (EIS) have been analyzed. The developed SbO-MoSnanocomposites electrode provides a high specific capacitance of 454.3 F gat the current density of 1 A g. Further, the hybrid supercapacitor device has been constructed which shows 104.04 F gof specific capacitance at 2 A gand manifests a good energy density of 24.42 Wh kgat a power density of 1299.89 W kg. Additionally, the hybrid device SbO-MoS//AC exhibits a good capacitive retention of 90.6% and a coulombic efficiency of 100.45% at 10 A gover 8000 cycles.

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Source
http://dx.doi.org/10.1088/1361-6528/ad6995DOI Listing

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