A method for the reduction of aldehydes with pinacolborane catalyzed by pincer cobalt complexes based on a triazine backbone is developed in this paper. The presented methodology allows for the transformation of several aldehydes bearing a wide range of electron-withdrawing and electron-donating groups under mild conditions. The presented procedure allows for the direct one-step hydrolysis of the obtained intermediates to the corresponding primary alcohols. A plausible reaction mechanism is proposed.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC11487440 | PMC |
| http://dx.doi.org/10.3390/ijms25147894 | DOI Listing |
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