Considering the challenges for both single and traditional two-stage treatments, advanced oxidation and biodegradation, in the treatment of actual coking wastewater, an intimately coupled catalytic ozonation and biodegradation (ICOB) reactor was developed. In this study, ICOB treatment significantly enhanced the removal of Cu, Fe, and color by 39 %, 45 %, and 52 %, respectively, outperforming biodegradation. Catalytic ozonation effectively breaking down unsaturated organic substances and high-molecular-weight dissolved organic matter into smaller, more biodegradable molecules. Compared with biodegradation, the ICOB system significantly increased the abundances of Pseudomonas, Sphingopyxis, and Brevundimonas by ∼ 96 %, ∼67 %, and ∼ 85 %, respectively. These microorganisms, possessing genes for degrading phenol, aromatic compounds, polycyclic aromatics, and sulfur metabolism, further enhanced the mineralization of intermediates. Consequently, the ICOB system outperformed biodegradation and catalytic ozonation treatments, exhibiting chemical oxygen demand removal rate of ∼ 58 % and toxicity reduction of ∼ 47 %. Overall, the ICOB treatment showcases promise for practical engineering applications in coking wastewater treatment.
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http://dx.doi.org/10.1016/j.biortech.2024.131154 | DOI Listing |
Water Res
January 2025
Yellow River Laboratory of Shanxi Province, Shanxi University, Taiyuan, 030006, PR China; The Key Laboratory of Water and Sediment Sciences (Ministry of Education), College of Environmental Sciences and Engineering, Peking University, Beijing, 100871, PR China. Electronic address:
High-temperature wastewaters can themselves activate peroxydisulfate (PDS) to remove aromatic contaminants via polymerization. This, however, may result in an insufficient carbon source for denitrification during biochemical treatment, and the formed polymers, without a proper reuse method, will be costly to handle as hazardous waste. This study demonstrates that the addition of NaOH can suppress the polymerization of aromatic contaminants, which is observed not only in simulated wastewater but also in actual coking wastewater (ACW).
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December 2024
Key Laboratory of the Three Gorges Reservoir Region's Eco-Environment, Ministry of Education, College of Environment and Ecology, Chongqing University, Chongqing 400045, China. Electronic address:
The peroxone reaction, a promising alternative technology for water treatment, is traditionally hampered by its restricted pH operational range and suboptimal oxidant utilization. In this study, we introduced a novel amphoteric metal oxide (ZnO)-regulated peroxone system that transcended the pH limitations of conventional peroxone processes. Our innovative approach exploited the unique properties of ZnO to regulate the reaction pathway of the traditional O/HO (or peroxymonosulfate, PMS) processes, resulting in a 52.
View Article and Find Full Text PDFEnviron Sci Technol
January 2025
CAS Key Laboratory of Urban Pollutant Conversion, Department of Environmental Science and Engineering, University of Science & Technology of China, Hefei 230026, China.
Organic pollutants removal via a polymerization transfer (PT) pathway based on the use of single-atom catalysts (SACs) promises efficient water purification with minimal energy/chemical inputs. However, the precise engineering of such catalytic systems toward PT decontamination is still challenging, and the conventional SACs are plagued by low structural stability of carbon material support. Here, we adopted magnesium oxide (MgO) as a structurally stable alternative for loading single copper (Cu) atoms to drive peroxymonosulfate-based Fenton-like reactions.
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December 2024
Shanghai Key Lab of Chemical Assessment and Sustainability, Key Laboratory of Yangtze River Water Environment, School of Chemical Science and Engineering, Tongji University, 1239 Siping Road, Shanghai 200092, PR China. Electronic address:
Selective conversion of organic pollutants in wastewater into value-added chemicals is a promising strategy for sustainable water management. Electrochemical processes offer attractive features of precise control over reaction pathway to achieve desired products, however, the traditional anode-mediated processes still face challenges of over-oxidation by the inevitably formed of hydroxyl radical (HO). Herein, we proposed a new cathode-mediated approach for selective conversion of phenol to p-benzoquinone (p-BQ) through peroxymonosulfate (PMS) activation.
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December 2024
National Engineering Research Center of Industrial Wastewater Detoxication and Resource Recovery, Beijing 100085, China; University of Chinese Academy of Sciences, Beijing 100049, China.
Resilience to increasing organic loading rates (OLRs) is the key to maintaining stable performance in treating industrial wastewater. First, this study compared the stability, particularly the nitrification performance, of two lab-scale moving bed biofilm reactors (MBBRs) filled with porous polyurethane biocarriers with two conventional activated sludge reactors (ASRs) in the treatment of synthetic coking wastewater under OLRs increasing from 0.3 kg to 1.
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