Feasibility of intimately coupled CaO-catalytic-ozonation and bio-contact oxidation reactor for heavy metal and color removal and deep mineralization of refractory organics in actual coking wastewater.

Bioresour Technol

Engineering Research Center of Low-Carbon Treatment and Green Development of Polluted Water in Northeast China, Ministry of Education, Northeast Normal University, Changchun 130117, Jilin, China; Jilin Engineering Lab for Water Pollution Control and Resources Recovery, Northeast Normal University, Changchun 130117, Jilin, China.

Published: September 2024

AI Article Synopsis

  • A new treatment method called the intimately coupled catalytic ozonation and biodegradation (ICOB) reactor was developed to address the challenges of treating coking wastewater.
  • The ICOB system significantly improved the removal rates of contaminants like copper, iron, and color, outperforming traditional biodegradation methods.
  • It also boosted the presence of beneficial microorganisms that can break down harmful substances, leading to higher mineralization rates and reduced toxicity in the treated wastewater.

Article Abstract

Considering the challenges for both single and traditional two-stage treatments, advanced oxidation and biodegradation, in the treatment of actual coking wastewater, an intimately coupled catalytic ozonation and biodegradation (ICOB) reactor was developed. In this study, ICOB treatment significantly enhanced the removal of Cu, Fe, and color by 39 %, 45 %, and 52 %, respectively, outperforming biodegradation. Catalytic ozonation effectively breaking down unsaturated organic substances and high-molecular-weight dissolved organic matter into smaller, more biodegradable molecules. Compared with biodegradation, the ICOB system significantly increased the abundances of Pseudomonas, Sphingopyxis, and Brevundimonas by ∼ 96 %, ∼67 %, and ∼ 85 %, respectively. These microorganisms, possessing genes for degrading phenol, aromatic compounds, polycyclic aromatics, and sulfur metabolism, further enhanced the mineralization of intermediates. Consequently, the ICOB system outperformed biodegradation and catalytic ozonation treatments, exhibiting chemical oxygen demand removal rate of ∼ 58 % and toxicity reduction of ∼ 47 %. Overall, the ICOB treatment showcases promise for practical engineering applications in coking wastewater treatment.

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Source
http://dx.doi.org/10.1016/j.biortech.2024.131154DOI Listing

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