The first two unprecedented high-nuclear wheel-hub-shaped transition-metal-doped polyoxovanadates, [MMoWVP] [M = Ni (), Co ()], have been assembled under solvothermal conditions. The center of the cluster consists of two {Ni(oa)} rings as the center hole, four {MoO} units acting as the spokes, and four {WV(PPOA)} molecular building blocks serving as the tire. Compound exhibits good catalytic properties and recyclability in oxidative desulfurization reactions.
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| http://dx.doi.org/10.1021/acs.inorgchem.4c02051 | DOI Listing |
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