Stable cyclic ether as an electrolyte additive for high-performance lithium metal batteries.

Chem Commun (Camb)

School of Materials Science and Engineering, Key Laboratory of Green Fabrication and Surface Technology of Advanced Metal Materials of Ministry of Education, Anhui University of Technology, Maanshan 243002, China.

Published: August 2024

Introducing a methyl group into 1,3-dioxolane (DOL) to obtain a stable cyclic ether, 4-methyl-1,3-dioxolane (4-Me DOL), allows it to be used as an additive in LiPF-based carbonate electrolytes. The addition of 4-Me DOL can form a stable SEI with good Li transport ability, which can simultaneously improve the rate capability and cycling performance of lithium metal batteries.

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Source
http://dx.doi.org/10.1039/d4cc03056gDOI Listing

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