Carbonate sediments are often regarded as problematic in geotechnical engineering due to the high variability of their properties. Understanding and quantifying this variability will become increasingly critical in the years ahead, notably with respect to upcoming developments in offshore renewable energy, for which limited in-situ data are typically available to characterise large areas. Here, six intervals from the North West Shelf of Australia, each composed of similar carbonate grains but accumulated in different environments, are investigated to better understand how the post-depositional cementation, alteration and dissolution of sediments, known as diagenesis, impact their geotechnical properties. Intervals are primarily affected by mineralogy-driven meteoric diagenesis, comprising in-situ dissolution of metastable grains and subsequent precipitation of cement that occurred when the shelf was exposed during lower sea-levels, and by marine diagenesis. In both cases, increased diagenesis results in a higher cement-to-solid ratio and compressive strength. However, while marine diagenesis is associated with a reduction in void ratio, this is not initially observed with mineralogy-driven meteoric diagenesis. Additionally, for a similar cement-to-solid ratio, microcrystalline cement results in higher compressive strength than sparite cement. The data further reveal that the level of meteoric cementation and the compressive strength increase as a function of the duration of exposure and of the regional climate, along with a reduction of the specific gravity related to the replacement of aragonite by calcite. However, increased meteoric diagenesis also leads to the formation of macro-scale heterogeneities such as calcrete layers and karsts that can affect the holistic geotechnical behaviour of such deposits.
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http://dx.doi.org/10.1038/s41598-024-67207-2 | DOI Listing |
Sci Rep
July 2024
Oceans Institute, The University of Western Australia, Crawley, WA, 6009, Australia.
Carbonate sediments are often regarded as problematic in geotechnical engineering due to the high variability of their properties. Understanding and quantifying this variability will become increasingly critical in the years ahead, notably with respect to upcoming developments in offshore renewable energy, for which limited in-situ data are typically available to characterise large areas. Here, six intervals from the North West Shelf of Australia, each composed of similar carbonate grains but accumulated in different environments, are investigated to better understand how the post-depositional cementation, alteration and dissolution of sediments, known as diagenesis, impact their geotechnical properties.
View Article and Find Full Text PDFProc Natl Acad Sci U S A
December 2022
Inorganic and Isotope Geochemistry, GFZ German Research Centre for Geosciences, 14473 Potsdam, Germany.
The O/O ratio of cherts (δO) increases nearly monotonically by ~15‰ from the Archean to present. Two end-member explanations have emerged: cooling seawater temperature (T) and increasing seawater δO (δO). Yet despite decades of work, there is no consensus, leading some to view the δO record as pervasively altered.
View Article and Find Full Text PDFSci Rep
January 2022
Department of Geological and Environmental Sciences, Western Michigan University, Kalamazoo, MI, 49008, USA.
Numerous Phanerozoic limestones are comprised of diagenetic calcite microcrystals formed during mineralogical stabilization of metastable carbonate sediments. Previous laboratory experiments show that calcite microcrystals crystallizing under conditions similar to those that characterize meteoric diagenetic settings (impurity-free, low degree of supersaturation, high fluid:solid ratio) exhibit the rhombic form/morphology, whereas calcite microcrystals crystallizing under conditions similar to those that prevail in marine and marine burial diagenetic settings (impurity-rich, high degree of supersaturation, low fluid:solid ratio) exhibit non-rhombic forms. Based on these experimental observations, it is proposed here that rhombic calcite microcrystals form exclusively in meteoric environments.
View Article and Find Full Text PDFHeliyon
December 2021
Department of Earth Sciences, Adekunle Ajasin University, Akungba-Akoko, Nigeria.
Petrographic and geochemical studies were undertaken on the Paleocene-Eocene limestones of the Ewekoro Formation in order to infer the depositional and post-depositional imprints on the limestone. Thin section petrographic studies revealed three distinct microfacies; grainstone, packstone and wackestone, and there were variations in the depositional environments from meteoric vadose to shallow marine environments with evidences of post-depositional processes of compaction, micritization and dolomitization. The total rare earth element concentration (ƩREE) of the limestone samples ranged from 39.
View Article and Find Full Text PDFHeliyon
July 2021
Kuwait University, Faculty of Science, Earth and Environmental Science Department, P.O. Box 5969, Safat, 13060, Kuwait.
Diagenetic changes are a concern in carbonate petroleum reservoir management. One of the challenges is to determine whether the pore systems are related to diagenesis and/or depositions, and how associated mechanisms affect reservoir quality. The purpose of this study was to assess variations in porosity and permeability due to diagenetic processes in the paleokarst zone of the Middle Eocene Upper Dammam Formation in Kuwait.
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