This study introduces a novel integrated quantitative modeling framework to assess the multiple environmental, health, and economic benefits from implementing carbon capture technology in the power sector of Basra province, Iraq. This province is struggling with significant environmental challenges and air pollution caused by extensive oil extraction operations. First, the developed modeling framework quantifies the captured CO emissions and the equivalent avoided PM emissions resulting from the use of carbon capture units in existing power plants. This is achieved through a detailed simulation of the monoethanolamine (MEA) capture process using Aspen. Second, the impact of avoided PM exposure on public health is evaluated by developing and applying a dynamic dispersion model across the districts where the power plants are located. Third, it quantifies the expected health benefits, using the health impact assessment method. This method is based on a comprehensive meta-analysis of concentration-response functions, and it utilizes a Recurrent Neural Network prediction framework based on the Long-Short Term Memory (LSTM) method to predict the relative risk value of six health outcomes. Finally, the economic value of avoided health burdens is estimated by employing the Value of Statistical Life (VSL) and the Cost of Illness (COI) approaches. According to the findings, implementing new carbon capture units in the selected power plants in the area will lead to a reduction of 7.697 million tons of carbon dioxide per year in the total emission of pollutants from the current power generation units in the region. The integrated assessment results demonstrate a significant reduction in PM emissions, amounting to 2299 tons per year, leading to the avoidance of 1328 premature deaths and 217 hospital admissions, resulting in annual savings of $1846 million from the avoided mortalities and morbidities cases and creation of 29,607 green jobs in Basra Province.
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http://dx.doi.org/10.1016/j.jenvman.2024.121848 | DOI Listing |
Environ Sci Pollut Res Int
January 2025
Institute for Integrated Energy Systems at University of Victoria (IESVic), Department of Mechanical Engineering, University of Victoria, Victoria, BC, V8P 5C2, Canada.
The world is increasingly facing the direct effects of climate change triggering warnings of a crisis for the healthy existence of humankind. The dominant driver of the climate emergency is the historical and continued accumulation of atmospheric CO altering net radiative forcing on the planet. To address this global issue, understanding the core chemistry of CO manipulation in the atmosphere and proximally in the oceans is crucial, to offer a direct partial solution for emissions handling through negative emissions technologies.
View Article and Find Full Text PDFNat Commun
January 2025
Department of Chemical Engineering, Worcester Polytechnic Institute, Worcester, MA, USA.
The economic feasibility of low-carbon ammonia production pathways, such as steam methane reforming with carbon capture and storage, biomass gasification, and electrolysis, is assessed under various policy frameworks, including subsidies, carbon pricing, and renewable hydrogen regulations. Here, we show that employing a stochastic techno-economic analysis at the plant level and a net present value approach under the US Inflation Reduction Act reveals that carbon capture and biomass pathways demonstrate strong economic potential due to cost-effectiveness and minimal public support needs. Conversely, the electrolytic pathway faces significant economic challenges due to higher costs and lower efficiency.
View Article and Find Full Text PDFACS Nano
January 2025
Yusuf Hamied Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW, U.K.
Carbon dioxide capture underpins an important range of technologies that can help to mitigate climate change. Improved carbon capture technologies that are driven by electrochemistry are under active development, and it was recently found that supercapacitor energy storage devices can reversibly capture and release carbon dioxide. So-called supercapacitive swing adsorption (SSA) has several advantages over traditional carbon dioxide capture technologies such as lower energy consumption and the use of nontoxic materials.
View Article and Find Full Text PDFEnviron Sci Technol
January 2025
State Key Laboratory of Heavy Oil Processing, Key Laboratory of Optical Detection Technology for Oil and Gas, College of Science, China University of Petroleum, Beijing 102249, PR China.
The purification efficiency of autoexhaust carbon strongly depends on the heterogeneous interface structure between active metal and oxide, which can modulate the local electronic structure of defect sites to promote the activation of reactant molecules. Herein, the high-dispersion CuO clusters supported on the well-defined CeO nanorods were prepared using the complex deposition slow method. The formation of heteroatomic Cu-O-Ce interfacial structural units as active sites can capture electrons to achieve activation of the NO and O molecules.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
Van 't Hoff Institute for Molecular Sciences, University of Amsterdam, 1098 XH Amsterdam, Netherlands.
We present the synthesis, structural analysis, and remarkable reactivity of the first carbon nanohoop that fully incorporates ferrocene in the macrocyclic backbone. The high strain imposed on the ferrocene by the curved nanohoop structure enables unprecedented photochemical reactivity of this otherwise photochemically inert metallocene complex. Visible light activation triggers a ring-opening of the nanohoop structure, fully dissociating the Fe-cyclopentadienyl bonds in the presence of 1,10-phenanthroline.
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