A new dicyanophenanthrene-based thermally activated delayed fluorophore: Design, synthesis, photophysical study, and electroluminescence application.

Spectrochim Acta A Mol Biomol Spectrosc

Guangdong Provincial Laboratory of Chemistry and Fine Chemical Engineering Jieyang Center, Jieyang, PR China; School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou, PR China; Analytical & Testing Center, Guangdong University of Technology, Guangzhou, PR China. Electronic address:

Published: December 2024

AI Article Synopsis

  • A new thermally activated delayed fluorescence (TADF) emitter called DCNP-SCF is created using a dicyanophenanthrene acceptor through a simple C-N coupling process.
  • The study examines the thermal, theoretical, photophysical, and electroluminescent properties of DCNP-SCF, highlighting its potential use in organic light-emitting devices.
  • DCNP-SCF's unique distorted donor-acceptor structure enhances its TADF and allows for efficient triplet harvesting, while its balanced electron push-pull effect improves its photoluminescence quantum yield, making it suitable for electroluminescent applications.

Article Abstract

A novel thermally activated delayed fluorescence (TADF) emitter, DCNP-SCF, is developed based on a dicyanophenanthrene acceptor. DCNP-SCF is prepared by a simple C-N coupling reaction. Its thermal, theoretical, photophysical, and electroluminescent properties are investigated, emphasizing its potential in organic electroluminescence devices. DCNP-SCF demonstrates highly distorted donor-acceptor conformation, facilitating significant TADF for efficient triplet harvesting in electroluminescence devices. Additionally, due to the moderate electron push-pull effect, DCNP-SCF exhibits appropriate intramolecular charge transfer for considerable photoluminescence quantum yield for electroluminescence applications.

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Source
http://dx.doi.org/10.1016/j.saa.2024.124808DOI Listing

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