AI Article Synopsis
- This study explores circularly polarized luminescence (CPL) from organic microcrystals, achieving a |g| value of up to 0.11.
- The microcrystals are created from emissive difluoroboron β-diketonate dyes combined with chiral binaphthol structures, which show strong CPL in solid form but none in solution.
- Findings reveal that the unique chiral arrangements impact electronic interactions, enhancing the optical properties of the dyes due to specific molecular stacking and orientation.
Article Abstract
Herein we report on circularly polarized luminescence (CPL) emission originating from supramolecular chirality of organic microcrystals with a |g| value up to 0.11. The microcrystals were prepared from highly emissive difluoroboron β-diketonate (BFdbk) dyes R-1 or S-1 with chiral binaphthol (BINOL) skeletons. R-1 and S-1 exhibit undetectable CPL signals in solution but manifest intense CPL emission in their chiral microcrystals. The chiral superstructures induced by BINOL skeletons were confirmed by single-crystal XRD analysis. Spectral analysis and theoretical calculations indicate that intermolecular electronic coupling, mediated by the asymmetric stacking in the chiral superstructures, effectively alters excited-state electronic structures and facilitates electron transitions perpendicular to BFbdk planes. The coupling increases cosθ from 0.05 (monomer) to 0.86 (tetramer) and triggers intense optical activity of BFbdk. The results demonstrate that optical activity of chromophores within assemblies can be regulated by both orientation and extent of intermolecular electronic couplings.
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| http://dx.doi.org/10.1002/anie.202407135 | DOI Listing |
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