Ru(PPh)Cl reacts with Bi from an ethylenediamine (en) solution of KBi to yield a new architype of 13-vertex [Bi{RuPPh}] () composed of unprecedented incomplete cuboidal Bi and triangular Bi held together by {RuPPh}.
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[Bi{RuPPh}]: Paramagnetic 13-Vertex Polybismuthide Heteroanion.
Inorg Chem
October 2024
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China.
Ru(PPh)Cl reacts with Bi from an ethylenediamine (en) solution of KBi to yield a new architype of 13-vertex [Bi{RuPPh}] () composed of unprecedented incomplete cuboidal Bi and triangular Bi held together by {RuPPh}.
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