AuBr Induces CsPb(Br/I) QDs to Self-Assemble into Nanowires.

Small Methods

Institute of Stomatology, School and Hospital of Stomatology, Wenzhou Medical University, Wenzhou, 325027, P. R. China.

Published: December 2024

Perovskite quantum dots can form various forms such as nanowires, nanorods, and nanosheets through self-assembly. Nanoscale self-assembly can be used to fabricate materials with excellent device properties. This study introduces AuBr into CsPb(Br/I) quantum dots, causing them to assemble into nanowires. The nanowires form because part of Au is surface-doped to replace Pb, and the [PbX6] octahedral structure is distorted. The symmetry of the structural surface is broken, and a dipole-moment-induced field is generated, thus promoting self-assembly. Moreover, the presence of Au nanoparticles (NPs) causes a localized surface plasmon resonance and generates strong van der Waals forces that promote self-assembly. Finally, to test other applications of perovskite nanowires, the solution method is used to prepare films by compounding the sample solution and polystyrene (PS) for backlighted displays.

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Source
http://dx.doi.org/10.1002/smtd.202400143DOI Listing

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