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Efficient recovery of highly pure CaF from fluorine-containing wastewater using an icy lime solution. | LitMetric

Efficient recovery of highly pure CaF from fluorine-containing wastewater using an icy lime solution.

Water Sci Technol

Key Laboratory of Green Utilization of Critical Non-metallic Mineral Resources, Ministry of Education, Wuhan University of Technology, Wuhan, Hubei 430070, China; School of Resources and Environmental Engineering, Wuhan University of Technology, Wuhan, Hubei 430070, China.

Published: July 2024

AI Article Synopsis

Article Abstract

Developing a feasible and low-cost strategy for the recovery of calcium fluoride efficiently from fluoride-containing wastewater is very essential for the recycle of fluoride resources. Herein, a modified lime precipitation method was employed to recover CaF from fluorinated wastewater using a special icy lime solution. Intriguingly, the highest F removal was greater than 95% under the optimal condition, leaving a fluoride concentration from 200 to 8.64 mg/L, while the lime dosage was much lower than that of industry. Importantly, spherical-shaped CaF particles with a 93.47% purity and size smaller than 600 nm were recovered, which has a high potential for the production of hydrofluoric acid. Besides, the precipitation was significantly affected by Ca/F molar ratio, stirring time, temperature, and solution pH. Furthermore, the thermodynamics and kinetics were investigated in detail to reveal the crystallization process. As a result, the defluorination reaction followed the pseudo-second order reaction kinetics model. Also, CO in the air adversely influenced the CaF purity. Based on this facile method, a high lime utilization efficiency was applied to defluorination, which contributed to protecting the environment and saving costs. This study, therefore, provides a feasible approach for the green recovery of fluorine resources and has significance for related research.

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Source
http://dx.doi.org/10.2166/wst.2024.211DOI Listing

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