Steel structures located in subtropical marine climates face harsh conditions such as strong sunlight and heavy rain, and they are extremely corroded. In this study, a waterborne coating with excellent corrosion resistance, hydrophobic ability, high-temperature resistance and high density was successfully prepared by using modified nanoscale titania powders and grafted polymers. The effects of three modifiers on titania nanoparticles and waterborne coatings' properties were studied independently. The experimental results showed that the activation index of the modification employing methacryloxy silane reached 97.5%, which achieved the best modification effect at 64.4 °C for 43.3 min. The waterborne coating with nanoscale titania modified by methacryloxy silane exhibited the best hydrophobic effect, with a drop contact angle of 115.4° and excellent heat resistance of up to 317.2 °C. The application of the waterborne modified coating in steel structures under subtropical maritime climates showed that the waterborne titania coatings demonstrated excellent resistance to corrosion, high temperatures and harsh sunlight, with a maximum service life of up to five years. Economic analysis indicated that, considering a conservative three-year effective lifespan, this coating could save more than 50% in cost compared with conventional industrial coatings. Finally, the strengthening mechanism of the polymer coatings with modified nanoscale titania was analyzed.
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http://dx.doi.org/10.3390/polym16131919 | DOI Listing |
Nanoscale
January 2025
Department of Materials Science and Engineering, Chair for Surface Science and Corrosion (WW4-LKO), Friedrich-Alexander-Universität Erlangen-Nürnberg, Martensstraße 7, 91058 Erlangen, Germany.
The photocatalytic degradation of unwanted organic species has been investigated for decades using modified and non-modified titania nanostructures. In the present study, we investigate the co-catalytic effect of single atoms (SAs) of Pt and Pt nanoparticles on titania substrates on the degradation of the two typical photodegradation model pollutants: Acid Orange 7 (AO7) and Rhodamine B (RhB). For this, we use highly defined sputter deposited anatase layers and load them with Pt SAs at different loading densities or alternatively with Pt nanoparticles.
View Article and Find Full Text PDFLangmuir
December 2024
Department of Aeronautics and Astronautics, Kyushu University, Motooka 744, Nishi-Ku, Fukuoka 819-0395, Japan.
Despite the importance of the effect of subnanoscale roughness on contact line behavior, it is difficult to directly observe the local behavior of contact lines at the micro- and nanoscale, leaving significant gaps in our current understanding. In this research, we investigate contact line motions and their relationship with nanoscale surface topography using coherence scanning interferometry. Our experiments were conducted on the substrates with different wettability without changing nanoscale surface topography.
View Article and Find Full Text PDFNanoscale
December 2024
Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China.
The high overpotential of the oxygen evolution reaction (OER) and the strong corrosion of the anode are the main problems currently faced by the zinc hydrometallurgical process. This study achieved the successful synthesis of titanium dioxide nanotubes doped by Al and V on a TC4 alloy. Subsequently, a composite electrode, TC4/AVTN-7/PbO-ZrO-CoO, was prepared utilizing composite electrodeposition.
View Article and Find Full Text PDFMaterials (Basel)
December 2024
Section of Condensed Matter Physics, Department of Physics, National and Kapodistrian University of Athens, University Campus, 15784 Athens, Greece.
The rational design of photonic crystal photocatalysts has attracted significant interest in order to improve their light harvesting and photocatalytic performances. In this work, an advanced approach to enhance slow light propagation and visible light photocatalysis is demonstrated for the first time by integrating a planar defect into CoO-TiO inverse opals. Trilayer photonic crystal films were fabricated through the successive deposition of an inverse opal TiO underlayer, a thin titania interlayer, and a photonic top layer, whose visible light activation was implemented through surface modification with CoO nanoscale complexes.
View Article and Find Full Text PDFIndian J Microbiol
December 2024
Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Halu Oleo, Kendari, 93232 Southeast Sulawesi Indonesia.
Cocoa pod production has experienced a significant decline due to attacks by the () fungus, which is the main cause of cocoa pod rot. To overcome this problem, Titanium dioxide (TiO) was chosen because of its potential as an antifungal, and its activity can be increased by adding silver nanoparticles (AgNPs). This research aims to determine the antifungal properties of TiO-Ag nanosuspension on the growth of under exposure to UV, Visible and without irradiation.
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