The graphene adjustable-barriers phototransistor is an attractive novel device for potential high speed and high responsivity dual-band photodetection. In this device, graphene is embedded between the semiconductors silicon and germanium. Both n-type and p-type Schottky contacts between graphene and the semiconductors are required for this device. While n-type Schottky contacts are widely investigated, reports about p-type Schottky contacts between graphene and the two involved semiconductors are scarce. In this study, we demonstrate a p-type Schottky contact between graphene and p-germanium. A clear rectification with on-off ratios of close to 10 (±5 V) and a distinct photoresponse at telecommunication wavelengths in the infrared are achieved. Further, p-type silicon is transferred to or deposited on graphene, and we also observe rectification and photoresponse in the visible range for some of these p-type Schottky junctions. These results are an important step toward the realization of functional graphene adjustable-barrier phototransistors.
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http://dx.doi.org/10.3390/nano14131140 | DOI Listing |
Phys Chem Chem Phys
January 2025
School of Physics and Optoelectronics, Xiangtan University, Xiangtan 411105, China.
Heterojunctions (HJs) based on two-dimensional (2D) transition metal dichalcogenides are considered promising candidates for next-generation electronic and optoelectronic devices. Here, vertical (V-type) and lateral (L-type) HJ diodes based on metallic 1T-VSe and semiconducting 2H-WSe with out-of-plane and in-plane contacts are designed. First-principles quantum transport simulations reveal that both V- and L-type VSe/WSe HJ diodes form p-type Schottky contacts.
View Article and Find Full Text PDFACS Omega
December 2024
Electrical Engineering, Indian Institute of Technology Gandhinagar, Gandhinagar 382055, India.
This work presents a density functional theory (DFT) study of substitutional and adsorption-based halogen (I or F) doping of WS-based transistors to enhance their contact properties. Substitutional doping of the WS monolayer with halogens results in -type behavior, while halogen adsorption on the surface of the WS monolayer induces -type behavior. This is attributed to differing directions of charge flow, as supported by the Mulliken analysis.
View Article and Find Full Text PDFNanomaterials (Basel)
December 2024
School of Materials Science and Engineering, Changchun University of Science and Technology, Changchun 130022, China.
Photocatalytic technology holds significant promise for sustainable development and environmental protection due to its ability to utilize renewable energy sources and degrade pollutants efficiently. In this study, BiOI nanosheets (NSs) were synthesized using a simple water bath method with varying amounts of mannitol and reaction temperatures to investigate their structural, morphological, photoelectronic, and photocatalytic properties. Notably, the introduction of mannitol played a critical role in inducing a transition in BiOI from an n-type to a p-type semiconductor, as evidenced by Mott-Schottky (M-S) and band structure analyses.
View Article and Find Full Text PDFACS Nano
December 2024
Department of Physics, Yonsei University, Seoul 03722, Republic of Korea.
To achieve the commercialization of two-dimensional (2D) semiconductors, the identification of an appropriate combination of 2D semiconductors and three-dimensional (3D) metals is crucial. Furthermore, understanding the van der Waals (vdW) interactions between these materials in thin-film semiconductor processes is essential. Optimizing these interactions requires precise control over the properties of the vdW interface through specific pre- or post-treatment methods.
View Article and Find Full Text PDFSmall
December 2024
State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals, Lanzhou University of Technology, Lanzhou, 730050, China.
Carbon-based hole transport layer (HTL)-free perovskite solar cells (C-PSCs) receive a lot of attention because of their simplified preparation technology, low price, and good hydrophobicity. However, the Schottky junction formed at the interface between perovskite and carbon poles affects the photogenerated carrier extraction and conversion efficiency. In this paper, 4-trifluoromethyl-2-pyridinecarboxylic acid (TPCA) is used to modify the perovskite films.
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