The properties of kagome metals are governed by the interdependence of band topology and electronic correlations resulting in remarkably rich phase diagrams. Here, we study the temperature evolution of the bulk electronic structure of the antiferromagnetic kagome metal FeGe using infrared spectroscopy. We uncover drastic changes in the low-energy interband absorption at the 100 K structural phase transition that has been linked to a charge-density-wave (CDW) instability. We explain this effect by the minuscule Fe displacement in the kagome plane, which results in parallel bands in the vicinity of the Fermi level. In contrast to conventional CDW materials, however, the spectral weight shifts to low energies, ruling out the opening of a CDW gap in FeGe.
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http://dx.doi.org/10.1103/PhysRevLett.132.266505 | DOI Listing |
Inorg Chem
December 2024
Department of Chemistry, Iowa State University, Ames, Iowa 50011, United States.
Investigating material properties is essential to assessing their application potential. While computational methods allow for a fast prediction of the material structure and properties, experimental validation is essential to determining the ultimate material potential. Herein, we report the synthesis and experimental magnetic properties of three previously reported Kagome compounds in the Li-Fe-Ge system.
View Article and Find Full Text PDFAcc Chem Res
December 2024
Faculty of Chemistry and Food Chemistry, TU Dresden, Bergstrasse 66c, 01069 Dresden, Germany.
ConspectusTriangulene (TRI) and its heterotriangulene (HT) derivatives are planar, triangle-shaped molecules that, via suitable coupling reactions, can form extended organic two-dimensional (2D) crystal (O2DC) structures. While TRI is a diradical, HTs are either closed-shell molecules or monoradicals which can be stabilized in their cationic form.Triangulene-based O2DCs have a characteristic honeycomb-kagome lattice.
View Article and Find Full Text PDFInorg Chem
December 2024
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou,Fujian 350002, China.
PbOCu(SeO)(NO)(OH) was synthesized by means of a replacement of (OH) groups for F ions of PbOCu(SeO)(NO)F, showing a transformation of kagomé and breathing kagomé lattices. Such a replacement did not change their intralayer ferromagnetic interactions and interlayer antiferromagnetic (AFM) interactions but slightly affected the Néel temperature and critical field, where PbOCu(SeO)(NO)(OH) possesses an AFM ordering at = 29.3 K, and a field-induced metamagnetic transition can occur at 2 K while a critical magnetic field of 1.
View Article and Find Full Text PDFJ Am Chem Soc
December 2024
Neutron Scattering Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, United States.
CoSn and FeSn, two kagome-lattice metals, have recently attracted significant attention as hosts of electronic flat bands and emergent physical properties. However, current understandings of their physical properties are limited to knowledge of the average crystal structure. Here, we report the Fe-doping induced coemergence of the antiferromagentic (AFM) order and local symmetry breaking in (CoFe)Sn.
View Article and Find Full Text PDFNat Nanotechnol
December 2024
The Institute for Solid State Physics, The University of Tokyo, Kashiwa, Japan.
Spintronics based on ferromagnets has enabled the development of microwave oscillators and diodes. To achieve even faster operation, antiferromagnets hold great promise despite their challenging manipulation. So far, controlling antiferromagnetic order with microwave currents remains elusive.
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