The Veneto Region (Northern Italy) conducted a monitoring campaign in the years 2016-2017 in order to evaluate the concentration of per- and polyfluoroalkyl substances (PFASs) in foods in the area affected by the water contamination discovered in 2013. The risk assessment for the resident population was conducted by the Italian National Institute of Health (ISS) in 2018 and updated in 2021. The European Food Safety Agency (EFSA) updated the limits used by ISS, in particular adding a limit for the sum of four PFAS molecules in 2020. In this work, the risk assessment conducted by ISS is reviewed in light of the new limit of 4.4 ng/kg body weight for the sum of perfluorooctanoic acid (PFOA), perfluorooctanesulfonic acid (PFOS), perfluorononanoic acid (PFNA), and perfluorohexanesulfonate (PFHxS). In the adult population (18-65 years), total weekly intakes, calculated for the years preceding 2013, resulted more than ten times the EFSA 2020 limit, more than five times in the intermediate period 2013-2017 - preceding the implementation of mitigation actions through double filtration of the water of the aqueduct -, by more than three times in the period after 2018, and yet by almost seven times for those who supply contaminated groundwater through private wells. The food contribution for those who use filtered water from the aqueduct is equal to 20% of the total weekly income.
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http://dx.doi.org/10.19191/EP24.3.A770.060 | DOI Listing |
Anal Chim Acta
March 2025
Department of Materials Science and Engineering, University of Utah, Salt Lake City, UT, 84112, USA. Electronic address:
Background: Perfluorooctane sulfonate (PFOS), one of the most harmful members of the large group of per- and poly-fluoroalkyl substances (PFAS), is notorious for its environmental persistence, bioaccumulation, and toxic effects, raising serious environmental and health concerns. Developing rapid and sensitive methods to detect PFOS in water is critical for effective monitoring and protection against this hazardous chemical.
Results: In this study, we developed rapid and highly sensitive fluorometric sensors (PDI-2+ , PDI-6+ ) for detecting PFOS.
Chemosphere
January 2025
Department of Preventive Medicine, College of Medicine, The Catholic University of Korea, Seoul, Republic of Korea; Environmental Health Center, College of Medicine, The Catholic University of Korea, Seoul, Republic of Korea. Electronic address:
Per- and polyfluoroalkyl substances (PFASs) are widely used in consumer products and are easily encountered in daily life. PFASs that accumulate in the human body can negatively affect adolescent health. This study aimed to identify key exposure pathways that influence serum PFAS levels in Korean adolescents, using data from the Korean National Environmental Health Survey (2018-2020) cycle 4.
View Article and Find Full Text PDFMar Pollut Bull
January 2025
School of Resources and Environment, Nanchang University, Key Laboratory of Poyang Lake Environment and Resource Utilization, Ministry of Education, Nanchang 330031, Jiangxi, China.
The widespread use of perfluoro/polyfluoroalkyl compounds (PFACs) makes it inevitable for them to be released into and affect the environment, and the octanol-water partition coefficient (logK) is a key indicator for evaluating the environmental behavior of trace pollutants and their impact on the environment. However, the determination of logK using experimental means is often time-consuming and laborious, or even unattainable. Therefore, the logKow of 20 per/polyfluoroalkyl compounds obtained from the PubChem database was selected as the object of study, and the 41 chemical descriptors required for modeling were obtained by density-functional theory calculations, and it was found that only two molecular descriptors (A, V) were significantly correlated with the logK, with the correlation of the descriptor A being the was the strongest.
View Article and Find Full Text PDFIntegr Environ Assess Manag
January 2025
Environmental Systems Analysis, Chalmers University of Technology, Gothenburg, Sweden.
This research aims to address the data gaps in freshwater ecotoxicological characterization factors (CFs) for per- and polyfluoroalkyl substances (PFASs). These CFs are essential for incorporating the ecotoxicity impacts of PFAS emissions into life cycle assessments (LCAs). This study has three primary objectives: first, to calculate a comprehensive set of experimental aquatic ecotoxicity CFs for PFASs utilizing the USEtox model (version 2.
View Article and Find Full Text PDFEnviron Health Perspect
January 2025
Department of Environmental Health, Boston University School of Public Health, Boston, Massachusetts, USA.
Background: Various countries have instituted risk governance measures to control and minimize the risks of chemicals at the national and international levels. Activities typically include risk assessment based on ) hazard and exposure assessments; ) setting limits on the production, use, and emissions of chemicals; ) enforcement of regulations; and ) monitoring the effectiveness of the measures taken. These steps largely depend on chemical analysis and access to pure chemical reference standards.
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