The corrosion behavior of carbon steel under the coexistence of carbon dioxide and SRB was studied by means of corrosion weight loss, SEM, EDS, in situ pH test, and other methods. The results showed that Chloride ions, temperature, pH, and oxygen coexist with iron bacteria will affect the corrosion under the coexistence of CO and SRB, and SRB tends to grow in a favorable environment for itself, and the corrosion rate of X52N at 42 days is slightly higher than that at 21 days. However, the pitting depth increased sharply from 21.20 µm in 21 days to 39.79 µm in 42 days. So that the corrosion can be divided into two stages. First, SRB catalyze the dissolution of FeCO, leading to local uniform corrosion. Second, SRB directly obtain electrons from the metal surface, resulting in local pitting. In addition, the environment under the stable mineralized biofilm was found to be slightly alkaline.
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http://dx.doi.org/10.1007/s11356-024-34328-0 | DOI Listing |
Heliyon
December 2024
Ingeniería Electroquímica y Corrosión, Instituto Unversitario de Seguridad Industrial, Radiofísica y Medioambiental, Universitat Politècnica de València, C/Camino de Vera s/n, 46022, Valencia, Spain.
In this research work, four distinct WO electrodes were synthesized and coated with three different polymers, known as polypyrrole (PPy), poly(3,4-ethylenedioxythiophene) in poly(4-styrenesulfonate) (PEDOT:PSS) and polyaniline (PANi), using electropolymerization techniques. The morphological features of the samples were thoroughly characterized through Field Emission Scanning Electron Microscopy (FE-SEM) and Atomic Force Microscopy (AFM) analyses. Additionally, contact angle measurements and electrochemical characterizations were used to verify the performance of each electrode, aiding in the prediction of their suitability for energy storage applications in lithium-ion batteries.
View Article and Find Full Text PDFMater Futur
March 2025
Advanced Materials Research Center, Department of Materials Engineering, Najafabad Branch, Islamic Azad University, Najafabad, Iran.
Magnesium (Mg) and its alloys are revolutionizing the field of interventional surgeries in the medical industry. Their high biocompatibility, biodegradability, and a similar elastic modulus to natural bone make porous Mg-based structures potential candidates for orthopedic implants and tissue engineering scaffolding. However, fabricating and machining porous Mg-based structures is challenging due to their complexity and difficulties in achieving uniform or gradient porosity.
View Article and Find Full Text PDFSci Rep
January 2025
Department of Physical Chemistry, Faculty of Chemistry, University of Tabriz, 29 Bahman Blvd., Tabriz, Iran.
Hydroxyapatite (HA) is an engineered biomaterial that closely resembles the hard tissue composition of humans. Biological HA is commonly non-stoichiometric and features lower crystallinity and higher solubility than stoichiometric HA. The chemical compositions of these biomaterials include calcium (Ca), phosphorus (P), and trace amounts of various ions such as magnesium (Mg), zinc (Zn), and strontium (Sr).
View Article and Find Full Text PDFJ Colloid Interface Sci
December 2024
Georgia Southern Univ, Dept Chem & Biochem, POB 8064, Statesboro, GA 30460, USA.
Great attentions have been paid to anticorrosion coatings with self-healing performances to enhance its reliability and protection period, but massive challenges still remain for developing a coating with selectively triggered and accurately controllable self-healing behaviors. Herein, by integrating lamellar graphene oxide (GO) into a polycaprolactone (PCL) nanofiber loaded with 8-hydroxyquinoline (8HQ) corrosion inhibitors, a composite coating with precisely controllable self-healing capabilities is developed. The coating defects can be remotely and accurately repaired under near-infrared (NIR) light irradiation within a very short time.
View Article and Find Full Text PDFAdv Sci (Weinh)
December 2024
School of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot, 010021, China.
The practical applications of aqueous Zn metal batteries are promising, yet still impeded by the corrosion reactions and dendrite growth on the Zn metal anode. Here, a self-adsorbed monolayer (SAM) is designed to stabilize the Zn metal anode. Theory and experiment results show that the interfacial confinement effect of the SAM, for one thing, greatly suppresses the corrosion reactions through the HO-poor inner Helmholtz plane because of the steric-hindrance effect, and for another, alleviates the Zn concentration gradient on the anode surface through the Zn enrichment behavior and eventually inhibits the dendrite growth.
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