A BODIPY-containing conjugated microporous polymer (CMP, LBFD-1) was modified with calixarene to develop a hydrophilic CMP (LBFD-2) with broader absorption extending to the near-infrared-II region. LBFD-2 exhibited an HO production rate of 2.14 mmol g h in the air without any sacrificial agents. The removal efficiency () of LBFD-2 towards methylene blue and rhodamine B reached >99.5% within 20 and 40 min in light. LBFD-2 can withstand diverse environmental changes, showing excellent reusability and potential for practical applications in real-water systems.
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| http://dx.doi.org/10.1039/d4cc02912g | DOI Listing |
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