Investigation of performance of potential adsorbents for emissions mitigation in a diesel generator.

Globally, the release of greenhouse gases primarily carbon dioxide (CO) emissions to our Earth's surface has climbed by  about 45% to its present atmospheric concentration rate of 420 parts per million (ppm) during the industrial era. An unprecedented rise in atmospheric CO concentration has been claimed to lead to significant factors such as global warming potential (GWP) and climate change effects.  An increase in atmospheric CO concentrations is  a  serious threat to the environment. Recent research efforts have focused on mitigating emissions from anthropogenic point sources. Adsorption-based post-combustion CO capture using solid adsorbents is the most effective and efficient method for mitigating gas adsorption in the exhaust system. In the current study, activated carbons are obtained from three potential biomass, namely, (i) coconut shell, (ii) rice husk, and (iii) eucalyptus wood, through a - single-stage activation method. The prepared activated carbon materials are analyzed using proximate and ultimate analyses. Further investigations are performed using different characterization techniques to ensure their adsorption efficiency. Adsorbents are packed one after the other in an in-house fabricated double adsorption chamber and coupled to the exhaust unit of a generator. Test experiments are conducted to examine adsorbents' capture efficiency in emissions mitigation. Adsorbents' adsorption parameters are evaluated in experimental investigations. At 2.5 bar and 50 °C, a maximum loading capacity of samples is achieved by 4.85 mmol/g, 4.58 mmol/g, and 5.96 mmol/g for coconut shell, rice husk, and eucalyptus wood adsorbents, respectively. With a post-combustion carbon adsorption chamber, CO and NO are captured about 40-64% and 38-58%, respectively, for all three adsorbents. The thermodynamic parameter of isosteric heat of adsorption value is below 40 kJ/mol, ensuring physisorption for all adsorbents.