Synthesis and photoluminescence properties of polymer chains based on pre-designed heterometallic AlLn molecular rings.

Chem Commun (Camb)

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China.

Published: July 2024

Presented herein is a series of chain compounds based on pre-designed heterometallic aluminum-lanthanide (Al-Ln) AlLn molecular rings. Their photoluminescence quantum yield (PLQY) with Eu (30.41%) and Tb (41.44%) is at a high level among the clusters containing four Ln ions. This study significantly extends the family of Al-Ln heterometallic clusters and demonstrates the synergistic effect of heterometallic ions in enhancing their properties.

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Source
http://dx.doi.org/10.1039/d4cc01611dDOI Listing

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