Droplet-based electricity generators (DEGs) are increasingly recognized for their potential in converting renewable energy sources. This study explores the interplay of surface hydrophobicity and stickiness in improving DEG efficiency. It find that the high-performance C-WaxDEGs leverage both these properties. Specifically, DEGs incorporating polydimethylsiloxane (PDMS) with carnauba wax (C-wax) exhibit increased output as surface stickiness decreases. Through experimental comparisons, PDMS with 1wt.% C-wax demonstrated a significant power output increase from 0.07 to 1.2 W m , which attribute to the minimized adhesion between water molecules and the polymer surface, achieved by embedding C-wax into PDMS surface to form microstructures. This improvement in DEG performance is notable even among samples with similar surface potentials and contact angles, suggesting that C-wax's primary contribution is in reducing surface stickiness rather than altering other surface properties. The further investigations into the C-WaxDEG variant with 1wt.% C-wax PDMS uncover its potential as a sensor for water quality parameters such as temperature, pH, and heavy metal ion concentration. These findings open avenues for the integration of C-WaxDEGs into flexible electronic devices aimed at environmental monitoring.
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http://dx.doi.org/10.1002/smll.202402765 | DOI Listing |
Bio Protoc
December 2024
Department of Electrical and Computer Engineering, Texas A & M University, College Station, TX, USA.
Droplet microfluidic platforms have been broadly used to facilitate DNA transfer in mammalian and bacterial hosts via methods such as transformation, transfection, and conjugation, as introduced in our previous work. Herein, we recapitulate our method for conjugal DNA transfer between strains in a droplet for increased conjugation efficiency and throughput of an otherwise laborious protocol. By co-incubating the donor and recipient strains in droplets, our method confines cells into close proximity allowing for increased cell-to-cell interactions.
View Article and Find Full Text PDFNat Chem Eng
October 2024
Department of Chemistry, University of Oxford, Oxford, UK.
Science
November 2024
Department of Chemistry, University of Oxford, Oxford, UK.
Hydrogel iontronic devices can emulate biological functions and communicate with living matter. But the fabrication of miniature, soft iontronic devices according to modular designs has not been achieved. In this work, we report the use of surfactant-supported assembly of freestanding microscale hydrogel droplets to construct various iontronic modules, circuits, and biointerfaces.
View Article and Find Full Text PDFSmall
November 2024
School of Integrated Circuits, Tsinghua University, Beijing, 100084, China.
Droplet-based electricity generator (DEG) is the promising energy harvesting technology applicable in versatile scenarios. Despite numerous optimizations in DEG's materials and structures, few has paid attention to the droplet dynamics and morphology control. Here the droplet's spread-retraction dynamics and the resultant semi Cassini oval (SCO) morphology are reported, characterized by convex at both ends and concave in the middle.
View Article and Find Full Text PDFLab Chip
November 2024
School of Engineering, Cardiff University, The Parade, Cardiff, CF24 3AA, UK.
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