Maltose Additive Enables Compacted Deposition of Zn Ions for Stabilizing the Zn Anode.

ACS Appl Mater Interfaces

School of Physical and Mathematical Sciences, Nanjing Tech University (NanjingTech), 30 South Puzhu Road, Nanjing 211816, China.

Published: July 2024

Aqueous zinc-ion batteries (AZIBs) have emerged as one of the most promising energy storage technologies due to their high safety and cost-effectiveness. However, several challenges associated with the Zn metal anode, such as dendrite growth, corrosion, and hydrogen evolution reaction (HER), have hindered further applications of AZIBs. Herein, maltose (MT) is used as a functional electrolyte additive to protect the Zn metal electrode during the interface deposition process. The additive can effectively affect the interface of Zn metal, suppressing HER and corrosion reactions. Moreover, it facilitates the uniform deposition of Zn by inducing Zn to form a stable (100) crystal plane. As a result, the symmetric cell exhibited stable cycling performance for 2000 h at a current density of 2 mA cm, and the Zn||NHVO full cell maintained steady cycling for 1000 cycles at 2 A g. This study provides an approach to achieve uniform Zn deposition through additives.

Download full-text PDF

Source
http://dx.doi.org/10.1021/acsami.4c07076DOI Listing

Publication Analysis

Top Keywords

uniform deposition
8
maltose additive
4
additive enables
4
enables compacted
4
deposition
4
compacted deposition
4
deposition ions
4
ions stabilizing
4
stabilizing anode
4
anode aqueous
4

Similar Publications

Electrolyte engineering has emerged as an effective strategy for stabilizing Zn-metal anodes. However, a single solute or solvent additive is far from sufficient to meet the requirements for electrolyte cycling stability. Here, we report a new-type high-entropy electrolyte composed of equal molar amounts of Zn(OTf)2 and LiOTf, along with equal volumes of H2O, triethyl phosphate, and dimethyl sulfoxide, which enhances electrolyte stability by increasing solvation entropy.

View Article and Find Full Text PDF

Efficient separation of photogenerated charge carriers is essential for maximizing the photocatalytic efficiency of semiconductor materials in oxygen evolution reactions (OER). This study presents a novel trimetallic photocatalyst, MIL-100(Fe)/TiO/CoO, synthesized through a facile microwave-assisted hydrothermal method followed by atomic layer deposition (ALD). The porous MIL-100(Fe) serves as a support for the sequential deposition of TiO and CoO layers ALD, which enhances electron-hole pair separation and minimizes their recombination.

View Article and Find Full Text PDF

The design of electrically conductive textiles appears to be a promising approach to combat the existing challenge of deaths caused by severe cold climates around the globe. However, reports on the scalable fabrication of tolerant conductive textiles maintaining a low electrical resistance with an ability for unperturbed and prolonged performance are scarce. Here, a breathable and wrappable water-repellent conductive textile (water-repellent CT) with electrothermal and photothermal conversion abilities at low external voltage and in weak solar light is introduced, respectively.

View Article and Find Full Text PDF

The cyclic stability of aqueous zinc-manganese batteries (ZMBs) is greatly restricted by the side reaction of the anode and the irreversibility of the cathode. In this work, a solid-liquid hybrid electrolyte mixing by traditional ZnSO-based electrolyte and diatomite (denoted as Dtm) is proposed that exhibits good compatibility and reversibility in both the anode interface and the cathode interface. The abundant hydroxyl groups at the anode interface disturb the hydrogen bond network of water molecule, which weakens the corrosion of the active water to Zn anode.

View Article and Find Full Text PDF

Gout is a disease caused by the deposit of monosodium urate (MSU) crystals that produce joint inflammation and subcutaneous nodules (tophi). The treatment of gout aims to reduce serum uric acid (sUA) levels by administering urate-lowering therapies (ULT) such as xanthine oxidase inhibitors (XOI: allopurinol, febuxostat) or uricosurics (e.g.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!