Transformation chemistry of atomically precise metal nanoclusters has emerged as a novel strategy for fundamental research on the structure-property correlations of nanomaterials. However, a thorough understanding of the transformation mechanism is indeed necessary to understand the structural growth patterns and corresponding property evolutions in nanoclusters. Herein, we present the ligand-exchange-induced transformation of the [Au(SR)] (8e) nanocluster to the [Au(SR')] (8e) nanocluster, through the Au(SR) (6e) intermediate species. Identification of this key intermediate through a partially reversible transformation helped in a detailed investigation into the transformation mechanism with atomic precision. Moreover, photophysical studies carried out on this Au(SR) species, which only differs by a single ligand from that of the [Au(SR)] nanocluster reveal the property evolutions at the slightest change in the nanocluster structure.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC11206343 | PMC |
| http://dx.doi.org/10.1039/d4sc01225a | DOI Listing |
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