Production of hydrogen (H) fuel using the hydrogen evolution reaction (HER) through electrocatalysis of water splitting is inexpensive, has optimal performance, and offers remarkable stability. Developing electrocatalysts with excellent stability and high efficiency has been a significant and challenging factor for practical applications of HER for decades. Hydrogen generation occurs on the HER electrode due to the emission of bubbles, proton diffusion, and the transfer of electrons. These considerations should be taken into account during the construction and development of the electrode. This review offers a synopsis of recent advancements in various electrodes used as a base for electrocatalysts, such as nickel foam, titanium foil, copper foam, carbon foam, and others, and discusses their HER catalytic activity, with a focus on the emission of bubbles, diffusion of ions, the structure of the electrode, and the formulation and preparation process. In conclusion, we provide an overview of ideas to further improve and address the significant issues in the manufacture of HER electrodes.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1002/cssc.202400847 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Retraction notice to "Stable and sustainable photoanodes using zinc oxide and cobalt oxide chemically gradient nanostructures for water-splitting applications" [Journal of Colloid And Interface Science 558 (2020) 9-20].
J Colloid Interface Sci
January 2025
Department of Emerging Materials Science, Daegu Gyeongbuk Institute of Science & Technology (DGIST), 333 Techno Jungang-daero, Hyeonpung-myeon, Dalseong-gun, Daegu 711-873, Republic of Korea. Electronic address:
Exploring P-(Fe,V)-Codoped Metastable-Phase β-NiMoO for Improving the Performance of Overall Water Splitting.
Inorg Chem
January 2025
School of Materials Science and Chemical Engineering, Ningbo University, Ningbo, Zhejiang 315211, P. R. China.
It is especially essential to develop high-performance and low-cost nonprecious metal catalysts for large-scale hydrogen production. A large number of electrochemical catalysts composited by transition metal centers has been reported; however, it is still a great challenge to design and manipulate target electrocatalysts to realize high overall water-splitting activity at the atomic level. Herein, we develop totally new P-(Fe,V)-codoped metastable-phase β-NiMoO.
View Article and Find Full Text PDFAtomic Imaging of the Surface Termination and Reconstruction of Low and High Index Iridium Oxide Surfaces and Insights into Their Facet-Dependent Oxygen Evolution Activities.
ACS Appl Mater Interfaces
January 2025
Institute of Materials Research, Tsinghua Shenzhen International Graduate School, Tsinghua University, Shenzhen 518055, Guangdong, PR China.
Resolving the atomic surface structure, particularly surface termination or reconstruction, is essential for understanding the catalytic properties of metal oxides. Although rutile phase iridium dioxide (IrO) is the state-of-the-art electrocatalyst for the oxygen evolution reaction (OER) in water splitting, the atomic-level surface structures of IrO remain largely unexplored, limiting our understanding of its facet-dependent OER activities. Herein, we perform aberration-corrected integrated differential phase contrast scanning transmission electron microscopy of the low- and high-index surface structures of spindle-shaped IrO nanorods and reveal distinct surface terminations and/or reconstructions on different surfaces.
View Article and Find Full Text PDFCreating Dual Active Sites in Ru-doped FeMn-MOF-74 for Efficient Overall Water Splitting.
Chemistry
January 2025
Southeast University, School of Chemistry and Chemical Engineering, Dongnan Daxue Road 2, 211189, Nanjing, CHINA.
The design of well-engineered bifunctional electrocatalysts is crucial for achieving durable and efficient performance in overall water splitting. In this study, Ru-doped FeMn-MOF-74 itself has Ru sites and generates FeMnOOH under catalytic conditions, forming dual active sites for overall water splitting. Density functional theory (DFT) calculations demonstrate that the Ru dopants exhibit optimized binding strength for H* and enhanced hydrogen evolution reaction (HER) performance.
View Article and Find Full Text PDFDistinct Promotion of PEC Water Oxidation of TaO/α-FeO/Co-Ni PBA via Coupling Ni 3d with O 2p.
Inorg Chem
January 2025
Eco-Materials and Renewable Energy Research Center (ERERC), College of Engineering and Applied Sciences, Nanjing University, Nanjing 210093, P. R. China.
The development of robust and effective photoanodes is crucial for photoelectrochemical hydrogen production via total water splitting. Herein, the TaO/α-FeO/Co-Ni PBA (TFPB-1) photoanode was constructed by the compositing n-type TaO and n-type α-FeO followed by the deposition of p-type Co-Ni PBA. The IPCE of TFPB-1 was increased to 35.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!