Ultrawide bandgap (UWBG) semiconductors, including GaO, diamond, Al Ga N/AlN, featuring bandgaps greater than 4.4 eV, hold significant promise for solar-blind ultraviolet photodetection, with applications spanning in environmental monitoring, chemical/biological analysis, industrial processes, and military technologies. Over recent decades, substantial strides in synthesizing high-quality UWBG semiconductors have facilitated the development of diverse high-performance solar-blind photodetectors (SBPDs). This review comprehensively examines recent advancements in UWBG semiconductor-based SBPDs across various device architectures, encompassing photoconductors, metal-semiconductor-metal photodetectors, Schottky photodiodes, p-n (p-i-n) photodiodes, phototransistors, etc., with a systematic introduction and discussion of their operational principles. The current state of device performance for SBPDs employing these UWBG semiconductors is evaluated across different device configurations. Finally, this review outlines key challenges to be addressed, aiming to steer future research endeavors in this critical domain.
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http://dx.doi.org/10.1021/acsomega.4c02897 | DOI Listing |
Nano Lett
January 2025
Zhejiang Provincial Engineering Research Center of Energy Optoelectronic Materials and Devices, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China.
Robust bipolar devices based on exclusively ultrawide bandgap (UWBG) semiconductors are highly desired for advanced power electronics. The heterojunction strategy has been a prevailing method for fabricating a bipolar device due to the lack of effective bipolar doping in the same UWBG material. Here, we demonstrate a unique heterojunction design integrating the p-type diamond and n-type ε-GaO that achieves remarkable breakdown voltages surpassing 3000 V.
View Article and Find Full Text PDFSci Adv
November 2024
Department of Chemical Engineering and Materials Science, University of Minnesota-Twin Cities, Minneapolis, MN 55455, USA.
Materials (Basel)
August 2024
Electrical and Computer Engineering, The University of Utah, Salt Lake City, UT 84112, USA.
ACS Appl Mater Interfaces
July 2024
Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials, Ministry of Education and School of Materials Science and Engineering, Shandong University, Jinan 250061, P. R. China.
Beta-gallium oxide (β-GaO) is emerging as a promising ultrawide band gap (UWBG) semiconductor, which is vital for high-power, high-frequency electronics and deep-UV optoelectronics. It is especially significant for flexible wearable electronics, enabling the fabrication of high-performance GaO-based devices at low temperatures. However, the limited crystallinity and pronounced structural defects arising from the low-temperature deposition of GaO films significantly restrict the heterojunction interface quality and the relevant electrical performance of GaO-based devices.
View Article and Find Full Text PDFACS Omega
June 2024
School of Future Technology, Henan Key Laboratory of Quantum Materials and Quantum Energy, Henan University, Zhengzhou 450046, P. R. China.
Ultrawide bandgap (UWBG) semiconductors, including GaO, diamond, Al Ga N/AlN, featuring bandgaps greater than 4.4 eV, hold significant promise for solar-blind ultraviolet photodetection, with applications spanning in environmental monitoring, chemical/biological analysis, industrial processes, and military technologies. Over recent decades, substantial strides in synthesizing high-quality UWBG semiconductors have facilitated the development of diverse high-performance solar-blind photodetectors (SBPDs).
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