Facile transmetalation is observed from a d metal, platinum(II), to indium and gallium leading to the extrusion of methylated gallate and indate anions representing a rare case of the "reverse" transmetalation from a d metal to a main group metal. The Pt-Ga and Pt-In bonding in the bimetallic complexes was analyzed through bosonic and fermionic potentials, QTAIM, and NBO.
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http://dx.doi.org/10.1039/d4cc02112f | DOI Listing |
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