Facile methyl group transfer from Pt to gallium and indium.

Chem Commun (Camb)

Coordination Chemistry and Catalysis Unit, Okinawa Institute of Science and Technology Graduate University, 1919-1 Tancha, Onna-son, 904-0495, Okinawa, Japan.

Published: July 2024

Facile transmetalation is observed from a d metal, platinum(II), to indium and gallium leading to the extrusion of methylated gallate and indate anions representing a rare case of the "reverse" transmetalation from a d metal to a main group metal. The Pt-Ga and Pt-In bonding in the bimetallic complexes was analyzed through bosonic and fermionic potentials, QTAIM, and NBO.

Download full-text PDF

Source
http://dx.doi.org/10.1039/d4cc02112fDOI Listing

Publication Analysis

Top Keywords

facile methyl
4
methyl group
4
group transfer
4
transfer gallium
4
gallium indium
4
indium facile
4
facile transmetalation
4
transmetalation observed
4
observed metal
4
metal platinumii
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!