An organophotoredox-catalyzed alkoxyallylation of feed-stock olefins, through thianthrenation using a Morita-Baylis-Hillman adduct as an allylating agent, is described. Site-selective addition of MeOH to an alkene-thianthrenium salt and its subsequent conversion into a nucleophilic radical species forms the basis of this unique difunctionalization strategy. The scope is also expanded into radical aryl allylation.
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| http://dx.doi.org/10.1039/d4cc01792g | DOI Listing |
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