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Recent Progress on Rechargeable Zn-X (X=S, Se, Te, I, Br) Batteries. | LitMetric

Recent Progress on Rechargeable Zn-X (X=S, Se, Te, I, Br) Batteries.

ChemSusChem

Shanghai Key Lab of Chemical Assessment and Sustainability, School of Chemical Science and Engineering, Tongji University, Shanghai, 200092, P. R. China.

Published: December 2024

AI Article Synopsis

  • Aqueous Zn-X batteries (ZXBs), which include zinc-sulfur, -selenium, -tellurium, -iodine, and -bromine variants, are gaining popularity for large-scale energy storage because of their high theoretical capacity and eco-friendly nature.
  • The review discusses the challenges in achieving high energy density in these batteries, emphasizing the need for improvements in cathode materials, reaction mechanisms, and electrolytes.
  • It also covers recent advancements in electrolyte design and its impact on performance, aiming to enhance understanding and guide future developments in ZXBs.

Article Abstract

Recently, aqueous Zn-X (X=S, Se, Te, I, Br) batteries (ZXBs) have attracted extensive attention in large-scale energy storage techniques due to their ultrahigh theoretical capacity and environmental friendliness. To date, despite tremendous research efforts, achieving high energy density in ZXBs remains challenging and requires a synergy of multiple factors including cathode materials, reaction mechanisms, electrodes and electrolytes. In this review, we comprehensively summarize the various reaction conversion mechanism of zinc-sulfur (Zn-S) batteries, zinc-selenium (Zn-Se) batteries, zinc-tellurium (Zn-Te) batteries, zinc-iodine (Zn-I) batteries, and zinc-bromine (Zn-Br) batteries, along with recent important progress in the design and electrolyte of advanced cathode (S, Se, Te, I, Br) materials. Additionally, we investigate the fundamental questions of ZXBs and highlight the correlation between electrolyte design and battery performance. This review will stimulate an in-deep understanding of ZXBs and guide the design of conversion batteries.

Download full-text PDF

Source
http://dx.doi.org/10.1002/cssc.202400886DOI Listing

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