This study aimed to evaluate the micro-mechanical and macro-mechanical properties of self-cured and light-cured alkasite and to investigate how accelerated degradation in acidic, alkaline, and ethanol solutions affects the macro-mechanical properties of self-cured and light-cured alkasite. The specimens of the alkasite material (Cention Forte, Ivoclar Vivadent) were prepared according to the following three curing modes: (1) light-cured immediately, (2) light-cured after a 5-min delay, and (3) self-cured. Microhardness was tested before and after immersion in absolute ethanol to indirectly determine crosslink density, while flexural strength and flexural modulus were measured using a three-point bending test after accelerated aging in the following solutions: (1) lactic acid solution (pH = 4.0), (2) NaOH solution (pH = 13.0), (3) phosphate-buffered saline solution (pH = 7.4), and (4) 75% ethanol solution. The data were statistically analyzed using a two-way ANOVA and Tukey post hoc test. The results showed that the microhardness, flexural strength, and flexural modulus were significantly lower in self-cured specimens compared to light-cured specimens. A 5-min delay between the extrusion of the material from the capsule and light curing had no significant effect on any of the measured properties. A significant effect of the accelerated aging solutions on macro-mechanical properties was observed, with ethanol and alkaline solutions having a particularly detrimental effect. In conclusion, light curing was preferable to self-curing, as it resulted in significantly better micro- and macro-mechanical properties, while a 5-min delay between mixing the capsule and light curing had no negative effects.
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http://dx.doi.org/10.3390/ma17112777 | DOI Listing |
Materials (Basel)
January 2025
Department of Architecture and Civil Engineering, City University of Hong Kong, Hong Kong.
This paper investigates the effects of particle morphology (PM) and particle size distribution (PSD) on the micro-macro mechanical behaviours of granular soils through a novel X-ray micro-computed tomography (μCT)-based discrete element method (DEM) technique. This technique contains the grain-scale property extraction by the X-ray μCT, DEM parameter calibration by the one-to-one mapping technique, and the massive derivative DEM simulations. In total, 25 DEM samples were generated with a consideration of six PSDs and four PMs.
View Article and Find Full Text PDFAdv Healthc Mater
January 2025
Key Laboratory of Biorheological Science and Technology (Chongqing University), Ministry of Education, State and Local Joint Engineering Laboratory for Vascular Implants, College of Bioengineering, Chongqing, 400044, P. R. China.
Decellularized artificial blood vessels prepared using physical and chemical methods often exhibit limitations, including poor mechanical performance, susceptibility to inflammation and calcification, and reduced patency. Cross-linking techniques can enhance the stiffness, as well as anti-inflammatory and anti-calcification properties of decellularized vessels. However, conventional cross-linking methods fail to effectively alleviate residual stress post-decellularization, which significantly impacts the patency and vascular remodeling following the implantation of artificial vessels.
View Article and Find Full Text PDFSci Rep
November 2024
School of Architectural Engineering, Neijiang Normal University, Neijiang, 641112, China.
The Cretaceous mudstone undergoes significant argillization and disintegration when in contact with water due to its high content of clay minerals, posing a severe challenge to the stability of roadways in coal mines during construction and operation. This research aimed to prepare water-sensitive mudstone-like materials by the method of clay mineral composition similar to that of natural Cretaceous mudstone to reproduce the mechanical and hydraulic properties of natural rocks and meanwhile reveal the deteriorating effect of clay minerals on its microstructure and macroscopic properties. Using binary clay-gypsum mixtures and considering the aggregate-binder ratio, the clay-gypsum ratio, the iron sand content in fine sand, and the powder sand content in aggregate as controlling factors, 16 groups of proportioning schemes were established using the orthogonal test method and a series of physic mechanical experiments were conducted to determine its mechanical and hydraulic properties.
View Article and Find Full Text PDFMaterials (Basel)
October 2024
College of Transportation Engineering, Nanjing Tech University, Nanjing 211816, China.
The rapid progress of urbanization and industrialization has led to the accumulation of large amounts of metal ions in the environment. These metal ions are adsorbed onto the negatively charged surfaces of clay particles, altering the total surface charge, double-layer thickness, and chemical bonds between the particles, which in turn affects the interactions between them. This causes changes in the microstructure, such as particle rearrangement and pore morphology adjustments, ultimately altering the mechanical behavior of the soil and reducing its stability.
View Article and Find Full Text PDFRSC Adv
August 2024
School of Food Science and Engineering, Hefei University of Technology Hefei Anhui 230009 P.R. China
The mechanisms of specific ion effects on the properties of amide macromolecules is essential to understanding the evolution of life. Because most biological macromolecules contain both complex hydrophilic and hydrophobic structures, it is challenging to accurately identify the contributions of molecular structure to macroscopic behaviors. Herein, we investigated the influence of specific ion effects on the mechanical behaviors of poly(-isopropylacrylamide) and neutral polyacrylamide (, PNIPAM and NPAM), through a cross-scale study that includes single-molecule force spectroscopy, molecular dynamics simulation and macro mechanical method.
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