Facile synthesis of Cu-based catalysts from CuSi and their catalysis properties study.

Chem Commun (Camb)

State Key Laboratory of Organic Electronics and Information Displays & Institute of Advanced Materials, Nanjing University of Posts & Telecommunications, 9 Wenyuan Road, Nanjing 210023, China.

Published: July 2024

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Supported copper species are well-known for their remarkable catalytic properties across numerous reactions. However, the current preparation methods pose challenges for large-scale production. In this study, we present a cost-effective method for the facile preparation of a series of copper-silicon composites using CuSi@Si particles as precursors. We evaluate the catalytic properties of these composites in the conversion of 4-nitrophenol to 4-amionphenol. Notably, the Cu@SiO/Si composite exhibits exceptional catalytic performance, attributed to the synergy effect between Cu and Si, and the formation of a metastable Si-H complex that enhances the reaction kinetics. This research introduces a novel approach for creating efficient and stable catalysts for hydrogenation reactions.

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http://dx.doi.org/10.1039/d4cc01870bDOI Listing

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