Inorganic elements in palm empty fruit bunch (EFB) are problematic in boiler operation, causing slagging and fouling deposits. The first pilot-scale hydrothermal treatment (HTT) system was commenced in a palm oil mill to remove undesirable elements. Fuel properties, combustion behavior, and fouling deposition of HTT-EFB were investigated. Liquid temperatures and treatment times in the HTT system significantly altered EFB-fuel properties. At ≥ 60 °C, potassium removals of at least 78 % were achieved, generating EFB-fuel containing potassium below 0.5 %wt. Later, a series of EFB combustion experiments were conducted in a specially designed fixed-bed reactor to simulate the tube surface of industrial boilers. Fouling deposition from HTT-EFB combustion reduced to below half of untreated EFB at all HTT conditions and combustion temperatures studied. The deposit-to-fuel ratio of HTT-EFB combusted at 1,000 °C was 37.3 % lower than untreated EFB combusted at a typical EFB boiler at 800 °C. Results demonstrated great potential for HTT-EFB in industrial applications.
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http://dx.doi.org/10.1016/j.biortech.2024.130969 | DOI Listing |
Anal Chim Acta
February 2025
School of Electric Power Engineering, South China University of Technology, Guangzhou, Guangdong, 510641, China; Guangdong Province Key Laboratory of Efficient and Clean Energy Utilization, Guangzhou, Guangdong, 510641, China. Electronic address:
Background: Rapid and accurate detection of the biomass potassium (K) content in biomass is crucial for mitigating ash deposition and fouling issues in biomass fuel combustion processes. Laser-induced breakdown spectroscopy (LIBS) offers a promising approach for rapid analysis of biomass elemental. However, the accuracy of LIBS detection is susceptible to chemical matrix effects.
View Article and Find Full Text PDFWater Res
January 2025
State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing 100084, China. Electronic address:
The almost hydrophobic PVDF membrane (PVDF matrix) commonly exhibited excellent performance in pollutant rejection but with poor anti-fouling performance. This study intended to develop the rejection performance and enhance anti-fouling of the PVDF membrane in an O/UF/BAC system for high quality water production through leveraging the advantages of in-situ ozonation and the nature of the PVDF membrane. Reduced density gradient (RDG) analysis demonstrated that the PVDF membrane exhibited excellent ozone resistance by reducing hydrogen bonds and electrostatic interactions between the membrane surface and ozone.
View Article and Find Full Text PDFLangmuir
January 2025
Department of Chemistry, School of Applied Sciences, REVA University, Bengaluru 560064, Karnataka, India.
Promethazine hydrochloride (PMHC) is a vital drug that is used as an anticholinergic, antipsychotic, antihistaminic, analgesic, sedative, and neuroleptic. However, the overdosage of PMHC also causes reproductive variations, cardiac changes, hypotension, and endocrinal variations. Hence, the detection of PMHC is crucial.
View Article and Find Full Text PDFWater Res
December 2024
State Key Laboratory of Pollution Control and Resource Reuse, College of Environmental Science and Engineering, Tongji University, Shanghai, 200092, PR China; Shanghai Institute of Pollution Control and Ecological Security, Tongji University, Shanghai, 200092, PR China.
Membrane separation technology has emerged as a highly energy-efficient method for microalgae enrichment and harvesting in wastewater treatment. However, membrane fouling caused by algal cells and stratified extracellular polymeric substances (EPS) remains a critical barrier to its industrial-scale application. This study meticulously investigates the micro process of algae-derived pollutants stacking to the membrane surface affected by stratified EPS.
View Article and Find Full Text PDFBioprocess Biosyst Eng
January 2025
Cell Culture Development, Biogen, 5000 Davis Drive, Research Triangle Park, NC, 27709, USA.
Membrane fouling is a common and complex challenge with cell culture perfusion process in biopharmaceutical manufacturing that can have detrimental effects on the process performance. In this study, we evaluated a method to calculate the hollow fiber membrane resistance at different time points for water and supernatant. In addition, the number of subvisible particles of < 200 nm.
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