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Loading and thermal behaviour of ZIF-8 metal-organic framework-inorganic glass composites. | LitMetric

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Article Abstract

Here we describe the synthesis of a compositional series of metal-organic framework crystalline-inorganic glass composites (MOF-CIGCs) containing ZIF-8 and an inorganic phosphate glass, 20NaO-10NaCl-70PO, to expand the library of host matrices for metal-organic frameworks. By careful selection of the inorganic glass component, a relatively high loading of ZIF-8 (70 wt%) was achieved, which is the active component of the composite. A Zn⋯O-P interfacial bond, previously identified in similar composites/hybrid blends, was suggested by analysis of the total scattering pair distribution function data. Additionally, CO and N sorption and variable-temperature PXRD experiments were performed to assess the composites' properties.

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http://dx.doi.org/10.1039/d4dt00894dDOI Listing

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